1.1.3.42: prosolanapyrone-II oxidase
This is an abbreviated version!
For detailed information about prosolanapyrone-II oxidase, go to the full flat file.
Word Map on EC 1.1.3.42
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1.1.3.42
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solani
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alternaria
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diels-alder
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diels-alderase
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iterative
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cycloaddition
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polyketide
- 1.1.3.42
- solani
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alternaria
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diels-alder
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diels-alderase
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iterative
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cycloaddition
- polyketide
Reaction
Synonyms
Sol5, solanapyrone synthase, SPS
ECTree
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Substrates Products
Substrates Products on EC 1.1.3.42 - prosolanapyrone-II oxidase
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REACTION DIAGRAM
prosolanapyrone II + O2
prosolanapyrone III + H2O2
the enzyme is involved in solanapyrone biosynthesis
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prosolanapyrone II + O2
prosolanapyrone III + H2O2
the bifunctional enzyme catalyses the oxidation of prosolanapyrone II and the subsequent cycloaddition of the product prosolanapyrone III to (-)-solanapyrone A
in an enzyme-catalyzed DielsAlder reaction the product prosolanapyrone III is isomerized to solanapyrone A (exo Diels-Alder cyclization, [4+2] cycloaddition). Solanapyrone D (endo Diels-Alder cyclization) is formed by a nonenzymatic Diels-Alder cyclization of prosolanopyrone III in polar solvents. The enzyme coverts prosolanapyrone II into solanapyrone A, solanapyrone D and prosolanapyrone III in the ratio 7:1:1
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?
prosolanapyrone II + O2
prosolanapyrone III + H2O2
the enzyme is involved in solanapyrone biosynthesis
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-
?
prosolanapyrone II + O2
prosolanapyrone III + H2O2
the bifunctional enzyme catalyses the oxidation of prosolanapyrone II and the subsequent cycloaddition of the product prosolanapyrone III to (-)-solanapyrone A
in an enzyme-catalyzed DielsAlder reaction the product prosolanapyrone III is isomerized to solanapyrone A (exo Diels-Alder cyclization, [4+2] cycloaddition). Solanapyrone D (endo Diels-Alder cyclization) is formed by a nonenzymatic Diels-Alder cyclization of prosolanopyrone III in polar solvents. The enzyme coverts prosolanapyrone II into solanapyrone A, solanapyrone D and prosolanapyrone III in the ratio 7:1:1
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