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1.13.11.1: catechol 1,2-dioxygenase

This is an abbreviated version!
For detailed information about catechol 1,2-dioxygenase, go to the full flat file.

Word Map on EC 1.13.11.1

Reaction

catechol
+
O2
=
cis,cis-muconate

Synonyms

(chloro-)catechol 1,2-dioxygenase, 1,2 CTD, 1,2-CTD, 1,2-pyrocatechase, 3-chlorocatechol 1,2-dioxygenase, BC-C23O, C1,2-DO, C1,2O, C12, C12D, C12DO, C12O, cat12, CatA, catechase, catechol 1,2 dioxygenase, catechol 1,2-dioxygenase, catechol 1,2-dioxygenase type I, catechol 1,2-dioxygenase type II, catechol 1,2-oxygenase, catechol dioxygenase, catechol oxygenase, catechol-oxygen 1,2-oxidoreductase, catechol:oxygen 1,2-oxidoreductase, CD I, CD II, CD-I, CD-II, CD-III-1, CD-III-2, CDI1, CDI2, chlorocatechol 1,2-dioxygenase, clCA, extradiol dioxygenase MhpB, IsoB, putative catechol 2,3-dioxygenase, pyrocatechase, pyrocatechol 1,2-dioxygenase, TfdC

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.1 catechol 1,2-dioxygenase

Substrates Products

Substrates Products on EC 1.13.11.1 - catechol 1,2-dioxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
1,2,3-trihydroxybenzene + O2
2-hydroxymuconate
show the reaction diagram
-
-
-
-
?
1,2,4-benzenetriol + O2
?
show the reaction diagram
-
52% activity compared to catechol
-
-
?
2,3-dihydroxybenzoic acid + O2
?
show the reaction diagram
-
-
-
?
3,4,5,6-tetrachlorocatechol + O2
?
show the reaction diagram
-
-
-
?
3,4-dihydroxybenzoic acid + O2
?
show the reaction diagram
3,4-dimethylcatechol + O2
3,4-dimethyl-cis,cis-muconate
show the reaction diagram
3,5-dichlorocatechol + O2
(2E,4E)-2,4-dichlorohexa-2,4-dienedioate
show the reaction diagram
3,5-dichlorocatechol + O2
?
show the reaction diagram
3,5-dimethylcatechol + O2
3,5-dimethyl-cis,cis-muconate
show the reaction diagram
3-butylcatechol + O2
2-butylhexa-2,4-dienedioic acid
show the reaction diagram
-
weak activity
-
-
?
3-chloro-5-methylcatechol + O2
2-chloro-4-methylhexa-2,4-dienedioate
show the reaction diagram
3-chlorocatechol + O2
2-chloro-cis,cis-muconate
show the reaction diagram
3-chlorocatechol + O2
?
show the reaction diagram
-
-
-
-
?
3-chloropyrocatechol + O2
?
show the reaction diagram
3-ethylcatechol + O2
2-ethyl-cis,cis-muconic acid
show the reaction diagram
3-isopropylcatechol + O2
2-isopropyl-cis,cis-muconate
show the reaction diagram
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
show the reaction diagram
3-methylcatechol + O2
2-methyl-cis,cis-muconate
show the reaction diagram
3-methylcatechol + O2
?
show the reaction diagram
3-methylpyrocatechol + O2
2,3,5-trimethyl-cis-cis-muconate
show the reaction diagram
3-methylthiocatechol + O2
2-methylthio-cis,cis-muconate
show the reaction diagram
-
very poor substrate
-
-
?
4,5-dichlorocatechol + O2
?
show the reaction diagram
4,5-difluorocatechol + O2
3,4-difluoro-cis-cis-muconate
show the reaction diagram
-
-
-
-
?
4-bromocatechol + O2
3-bromo-cis-cis-muconate
show the reaction diagram
4-chloro-5-fluorocatechol + O2
?
show the reaction diagram
-
-
-
-
?
4-chlorocatechol + O2
(2E,4Z)-3-chlorohexa-2,4-dienedioate
show the reaction diagram
4-chlorocatechol + O2
4-chloro-cis,cis-muconate
show the reaction diagram
4-chlorocatechol + O2
4-chlorocis,cis-muconate
show the reaction diagram
-
-
-
-
?
4-chlorocatechol + O2
?
show the reaction diagram
4-ethylcatechol + O2
4-ethyl-cis-cis-muconate
show the reaction diagram
-
42% of activity with catechol
-
-
?
4-fluorocatechol + O2
3-fluoro-cis,cis-muconate
show the reaction diagram
4-fluorocatechol + O2
4-fluoro-cis,cis-muconate
show the reaction diagram
-
65% of activity with catechol
-
-
?
4-hydroxybenzoic acid + O2
?
show the reaction diagram
4-iso-propylcatechol + O2
4-isopropyl-cis,cis-muconate
show the reaction diagram
-
23% of activity with catechol
-
-
?
4-methylcatechol + O2
(2Z,4Z)-3-methylhexa-2,4-dienedioate
show the reaction diagram
4-methylcatechol + O2
3-methyl-cis,cis-hexadienedioate
show the reaction diagram
-
-
-
?
4-methylcatechol + O2
3-methyl-cis,cis-muconate
show the reaction diagram
4-methylcatechol + O2
3-methylhexa-2,4-dienedioate
show the reaction diagram
4-methylcatechol + O2
4-methyl-cis,cis-muconate
show the reaction diagram
4-methylcatechol + O2
?
show the reaction diagram
4-methylpyrocatechol + O2
2,4,5-trimethyl-cis-cis-muconate
show the reaction diagram
4-n-propylcatechol + O2
4-n-propyl-cis,cis-muconate
show the reaction diagram
-
17% of activity with catechol
-
-
?
4-nitrocatechol + O2
?
show the reaction diagram
-
80% activity compared to catechol
-
-
?
4-tert-butylcatechol + O2
?
show the reaction diagram
benzene-1,2,4-triol + O2
?
show the reaction diagram
benzoate + O2
?
show the reaction diagram
-
-
-
-
?
benzoic acid + O2
?
show the reaction diagram
-
-
-
?
catechol + ?
?
show the reaction diagram
catechol + O2
cis,cis-muconate
show the reaction diagram
catechol + O2
cis,cis-muconic acid
show the reaction diagram
catechol + O2
cis-cis muconate
show the reaction diagram
assay at pH 8.0, 30°C
-
-
?
hydroxyquinol + O2
?
show the reaction diagram
i.e. 1,2,4-trihydroxy benzene
-
-
?
hydroxyquinol + O2
maleylacetic acid
show the reaction diagram
phenol + O2
?
show the reaction diagram
protocatechuate + O2
?
show the reaction diagram
i.e. 3,4-dihydroxybenzoate
-
-
?
pyrocatechol + O2
2,5-dimethyl-cis-cis-muconate
show the reaction diagram
pyrogallol + O2
?
show the reaction diagram
pyrogallol + O2
alpha-hydroxymuconic acid
show the reaction diagram
tetrachlorocatechol + O2
cis,cis-tetrachloromuconic acid
show the reaction diagram
-
-
-
-
?
additional information
?
-