1.13.11.74: 2-aminophenol 1,6-dioxygenase
This is an abbreviated version!
For detailed information about 2-aminophenol 1,6-dioxygenase, go to the full flat file.
Word Map on EC 1.13.11.74
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1.13.11.74
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2-aminomuconic
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dioxygenases
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nitrobenzene
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fission
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extradiol
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6-semialdehyde
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alpha-subunits
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protocatechuate
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beta-subunits
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comamonas
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meta-cleavage
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dioxygenation
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suicide
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catecholic
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pseudoalcaligenes
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4-nitrocatechol
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homoprotocatechuate
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mutase
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wastewater
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4-oxalocrotonate
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2-his-1-carboxylate
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facial
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nonhaem
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nitroreductase
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alpha2beta2
- 1.13.11.74
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2-aminomuconic
- dioxygenases
- nitrobenzene
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fission
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extradiol
- 6-semialdehyde
- alpha-subunits
- protocatechuate
- beta-subunits
- comamonas
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meta-cleavage
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dioxygenation
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suicide
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catecholic
- pseudoalcaligenes
- 4-nitrocatechol
- homoprotocatechuate
- mutase
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wastewater
- 4-oxalocrotonate
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2-his-1-carboxylate
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facial
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nonhaem
- nitroreductase
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alpha2beta2
Reaction
Synonyms
2-aminophenol-1,6-dioxygenase, amnA, amnB, amnBA, APD
ECTree
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Substrates Products
Substrates Products on EC 1.13.11.74 - 2-aminophenol 1,6-dioxygenase
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REACTION DIAGRAM
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1.3% activity compared to 2-aminophenol
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2-amino-4,5-dimethylphenol + O2
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1.3% activity compared to 2-aminophenol
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?
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15% activity compared to 2-aminophenol
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2-amino-4-chlorophenol + O2
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15% activity compared to 2-aminophenol
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2-amino-4-chlorophenol + O2
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6.8% activity compared to 2-aminophenol
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2-amino-4-chlorophenol + O2
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6.8% activity compared to 2-aminophenol
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?
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68% activity compared to 2-aminophenol
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2-amino-5-chlorophenol + O2
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68% activity compared to 2-aminophenol
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2-amino-m-cresol + O2
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1% activity compared to 2-aminophenol
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?
2-aminophenol + O2
2-aminomuconate 6-semialdehyde
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?
2-aminophenol + O2
2-aminomuconate 6-semialdehyde
100% activity
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?
2-aminophenol + O2
2-aminomuconate 6-semialdehyde
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?
2-aminophenol + O2
2-aminomuconate 6-semialdehyde
100% activity
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2-aminophenol + O2
2-aminomuconate 6-semialdehyde
O34137; O24680
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2-aminophenol + O2
2-aminomuconate 6-semialdehyde
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100% activity
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2-aminophenol + O2
2-aminomuconate 6-semialdehyde
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100% activity
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2-aminophenol + O2
2-aminomuconate 6-semialdehyde
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2-aminophenol + O2
2-aminomuconate 6-semialdehyde
O34137; O24680
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25% activity compared to 2-aminophenol
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catechol + O2
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O34137; O24680
suicide substrate of 2-aminophenol 1,6-dioxygenase
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catechol + O2
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O34137; O24680
suicide substrate of 2-aminophenol 1,6-dioxygenase
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?
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33% activity compared to 2-aminophenol
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protocatechuate + O2
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33% activity compared to 2-aminophenol
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?
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5% activity with catechol
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additional information
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5% activity with catechol
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additional information
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3-methylcatechol, 4-methylcatechol, 3-chlorocatechol, 4-chlorocatechol, 1,2,3-trihydroxybenzene, 1,2,4-trihydroxybenzene, 4-aminoresorcinol, 2-amino-p-cresol, 2,3-dihydroxybenzoic acid, protocatechuate, 2-methoxyphenol, 4-amino-3-hydroxybenzoic acid, 3-amino-4-hydroxybenzoic acid, 3-hydroxyanthranilic acid, and 4-amino-m-cresol are no substrates
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?
additional information
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ternary iron(II)-2-aminophenolate complexes (TpPh,Me)FeII(2-amino-4-tert-butylphenolate) and (TpPh,Me)FeII(2-amino-4,6-di-tert-butylphenolate) closely mimic the active site structure of the enzyme and at the same time displays C-C cleavage activity
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additional information
?
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3-methylcatechol, 4-methylcatechol, 3-chlorocatechol, 4-chlorocatechol, 1,2,3-trihydroxybenzene, 1,2,4-trihydroxybenzene, 4-aminoresorcinol, 2-amino-p-cresol, 2,3-dihydroxybenzoic acid, protocatechuate, 2-methoxyphenol, 4-amino-3-hydroxybenzoic acid, 3-amino-4-hydroxybenzoic acid, 3-hydroxyanthranilic acid, and 4-amino-m-cresol are no substrates
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additional information
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ternary iron(II)-2-aminophenolate complexes (TpPh,Me)FeII(2-amino-4-tert-butylphenolate) and (TpPh,Me)FeII(2-amino-4,6-di-tert-butylphenolate) closely mimic the active site structure of the enzyme and at the same time displays C-C cleavage activity
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additional information
?
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no activity with phenol, o-, m-, or p-cresol, aniline, o-, m-, or p-aminobenzoic acid, o-, m-, or p-phenylenediamine, protocatechuic acid, 2,3-dihydroxybenzoic acid, 3-aminophenol, 4-aminophenol, 2-amino-4-isopropylphenol, 2-amino-tert-butylphenol, 3-aminophenazin-2-ol, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 3-amino-4-hydroxybenzoic acid, or 4-amino-3-hydroxybenzoic acid, amidol and 3-hydroxyanthralinic acid
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additional information
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no activity with phenol, o-, m-, or p-cresol, aniline, o-, m-, or p-aminobenzoic acid, o-, m-, or p-phenylenediamine, protocatechuic acid, 2,3-dihydroxybenzoic acid, 3-aminophenol, 4-aminophenol, 2-amino-4-isopropylphenol, 2-amino-tert-butylphenol, 3-aminophenazin-2-ol, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 3-amino-4-hydroxybenzoic acid, or 4-amino-3-hydroxybenzoic acid, amidol and 3-hydroxyanthralinic acid
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