1.13.11.9: 2,5-dihydroxypyridine 5,6-dioxygenase
This is an abbreviated version!
For detailed information about 2,5-dihydroxypyridine 5,6-dioxygenase, go to the full flat file.
Word Map on EC 1.13.11.9
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1.13.11.9
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putida
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copperi
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dopamine
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deformylase
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alpha-hydroxylating
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peptidylglycine
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beta-monooxygenase
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biotechnology
- 1.13.11.9
- putida
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copperi
- dopamine
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deformylase
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alpha-hydroxylating
- peptidylglycine
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beta-monooxygenase
- biotechnology
Reaction
Synonyms
2,5-DHP dioxygenase, 2,5-dihydroxypyridine dioxygenase, 2,5-dihydroxypyridine oxygenase, 2,5DHP dioxygenase, EC 1.13.1.9, NicX, NicX protein, oxygenase, 2,5-dihydroxypyridine 5,6-di-, pyridine-2,5-diol dioxygenase
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Natural Substrates Products
Natural Substrates Products on EC 1.13.11.9 - 2,5-dihydroxypyridine 5,6-dioxygenase
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REACTION DIAGRAM
2,5-dihydroxypyridine + O2
N-formylmaleamic acid
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activation with 10 mM DTT and 0.5 mM FeSO4 (25 min, 25°C)
ring cleavage between carbon 5 and 6, further conversion to formic and maleamic acid is catalyzed by the NicD protein, a deformylase similar to some members of the alpha/beta-hydolase fold superfamily
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?
2,5-dihydroxypyridine + O2
N-formylmaleamic acid
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aerobic catabolism of nicotinic acid
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2,5-dihydroxypyridine + O2
N-formylmaleamic acid
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activation with 10 mM DTT and 0.5 mM FeSO4 (25 min, 25°C)
ring cleavage between carbon 5 and 6, further conversion to formic and maleamic acid is catalyzed by the NicD protein, a deformylase similar to some members of the alpha/beta-hydolase fold superfamily
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?
2,5-dihydroxypyridine + O2
N-formylmaleamic acid
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aerobic catabolism of nicotinic acid
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maleamate + formate
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nicotinic acid catabolism
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2,5-dihydroxypyridine + O2 + H2O
maleamate + formate
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nicotinic acid catabolism
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2,5-dihydroxypyridine + O2 + H2O
maleamate + formate
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nicotinic acid catabolism
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aerobic nicotinic acid degradation, nice gene cluster is responsible for the aerobic nicotinic acid degradation
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additional information
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aerobic nicotinic acid degradation, nice gene cluster is responsible for the aerobic nicotinic acid degradation
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