1.14.11.44: (R)-dichlorprop dioxygenase (2-oxoglutarate)
This is an abbreviated version!
For detailed information about (R)-dichlorprop dioxygenase (2-oxoglutarate), go to the full flat file.
Word Map on EC 1.14.11.44
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1.14.11.44
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herbicide
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aryloxyalkanoate
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maize
-
2,4-dichlorophenoxyacetic
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aryloxyphenoxypropionate
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corn
-
grain
-
weed
-
accase
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near-isogenic
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non-gm
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herbicide-tolerant
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glyphosate-resistant
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toxicological
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sugarcane
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auxin
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bacilliform
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non-transgenic
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enantioselective
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glyphosate
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ubiquitin
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sphingobium
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quizalofop-p-ethyl
-
carboxylase
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agronomically
- 1.14.11.44
-
herbicide
-
aryloxyalkanoate
- maize
-
2,4-dichlorophenoxyacetic
-
aryloxyphenoxypropionate
- corn
- grain
-
weed
- accase
-
near-isogenic
-
non-gm
-
herbicide-tolerant
-
glyphosate-resistant
-
toxicological
- sugarcane
- auxin
-
bacilliform
-
non-transgenic
-
enantioselective
- glyphosate
- ubiquitin
-
sphingobium
-
quizalofop-p-ethyl
- carboxylase
-
agronomically
Reaction
Synonyms
(R)-phenoxypropionate/alpha-ketoglutarate-dioxygenase, 2-oxoglutarate-dependent (R)-dichlorprop dioxygenase, AAD-1, alpha-ketoglutarate-dependent (R)-dichlorprop dioxygenase, ariloxyalkanoate-dioxygenase-1, RdpA
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Natural Substrates Products
Natural Substrates Products on EC 1.14.11.44 - (R)-dichlorprop dioxygenase (2-oxoglutarate)
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REACTION DIAGRAM
(R)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
(R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
4-chloro-2-methylphenol + pyruvate + succinate + CO2
2,4-dichlorophenol + pyruvate + succinate + CO2
i.e. (R)-dichlorprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). RdpA is highly specific for the cleavage of the R-configuration of dichlorprop and mecoprop
-
-
?
(R)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
i.e. (R)-dichlorprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). RdpA is highly specific for the cleavage of the R-configuration of dichlorprop and mecoprop
-
-
?
(R)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
i.e. (R)-dichlorprop, the enzyme is involved in the degradation of phenoxyalkanoic acid herbicides in Sphingomonas herbicidovorans MH
-
-
?
(R)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2
2,4-dichlorophenol + pyruvate + succinate + CO2
the enzyme catalyzes the initial step of microbial degradation of the chiral herbicide (R,S)-2-(2,4-dichlorophenoxy)propionate (R,S-dichlorprop)
-
-
?
4-chloro-2-methylphenol + pyruvate + succinate + CO2
i.e. (R)-mecoprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). RdpA is highly specific for the cleavage of the R-configuration of dichlorprop and mecoprop
-
-
?
(R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
4-chloro-2-methylphenol + pyruvate + succinate + CO2
i.e. (R)-mecoprop, the enzyme is involved in degrading the chiral herbicides (RS)-2-(2,4-dichlorophenoxy)propionate (dichlorprop) and (RS)-2-(4-chloro-2-methylphenoxy)propionate (mecoprop). RdpA is highly specific for the cleavage of the R-configuration of dichlorprop and mecoprop
-
-
?
(R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
4-chloro-2-methylphenol + pyruvate + succinate + CO2
-
-
-
?
(R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
4-chloro-2-methylphenol + pyruvate + succinate + CO2
i.e. (R)-mecoprop, the enzyme is involved in the degradation of phenoxyalkanoic acid herbicides in Sphingomonas herbicidovorans MH
-
-
?
(R)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2
4-chloro-2-methylphenol + pyruvate + succinate + CO2
-
-
-
?