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1.14.13.160: (2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA 1,5-monooxygenase

This is an abbreviated version!
For detailed information about (2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA 1,5-monooxygenase, go to the full flat file.

Word Map on EC 1.14.13.160

Reaction

[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA
+
O2
+
NADPH
+
H+
=
[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA
+
NADP+
+
H2O

Synonyms

2-oxo-DELTA3-4,5,5-trimethylcyclopentenyl-acetyl-CoA monooxygenase, 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA 1,2-monooxygenase, 2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA monooxygenase, OTEMO

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.13.160 (2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA 1,5-monooxygenase

Substrates Products

Substrates Products on EC 1.14.13.160 - (2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA 1,5-monooxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(+-)-cis-bicyclo[3.2.0]hept-2-en-6-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
2,3,4,5-tetramethyl-2-cyclopenten-1-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
2-cyclohexen-1-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
2-cyclopenten-1-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
62% conversion
-
-
?
2-ethylcyclopentanone + O2 + NADPH + H+
6-ethyltetrahydro-2H-pyran-2-one + NADP+ + H2O
show the reaction diagram
2-methylcyclohexanone + O2 + NADPH + H+
7-methyloxepan-2-one + NADP+ + H2O
show the reaction diagram
2-n-hexylcyclopentanone + O2 + NADPH + H+
6-hexyltetrahydro-2H-pyran-2-one + NADP+ + H2O
show the reaction diagram
2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetic acid + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
-
-
-
?
2-oxo-DELTA3-4,5,5-trimethylcyclopentenylacetyl-CoA + O2 + NADPH + H+
delta-lactone of 5-hydroxy-3,4,4-trimethyl-A2-pimelyl-CoA + NADP+ + H2O
show the reaction diagram
2-oxocyclopentyl acetic acid + O2 + NADPH + H+
(6-oxotetrahydro-2H-pyran-2-yl)acetic acid + NADP+ + H2O
show the reaction diagram
-
-
-
?
2-oxocyclopentyl ethyl acetate + O2 + NADPH + H+
ethyl (6-oxotetrahydro-2H-pyran-2-yl)acetate + NADP+ + H2O
show the reaction diagram
-
-
-
?
3,5,5-trimethyl-2-cyclohexen-1-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
3-methyl-2-cyclohexen-1-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
3-methyl-2-cyclopenten-1-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
13% conversion
-
-
?
4-methylcyclohexanone + O2 + NADPH + H+
5-methyloxepan-2-one + NADP+ + H2O
show the reaction diagram
-
-
-
?
bicyclo[3.2.0]hept-2-en-6-one + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
-
products are a mixture of normal to abnormal lactone at a ratio of 3:1
-
?
cyclobutanone + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
-
-
-
?
norcamphor + O2 + NADPH + H+
? + NADP+ + H2O
show the reaction diagram
-
-
-
?
[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA + O2 + NADPH + H+
[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA + NADP+ + H2O
show the reaction diagram
additional information
?
-