1.14.99.47: (+)-larreatricin hydroxylase
This is an abbreviated version!
For detailed information about (+)-larreatricin hydroxylase, go to the full flat file.
Reaction
Synonyms
larreatricin 3'-hydroxylase, larreatricin 3-hydroxylase, More, PPO
ECTree
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Substrates Products
Substrates Products on EC 1.14.99.47 - (+)-larreatricin hydroxylase
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REACTION DIAGRAM
(+)-larreatricin + O2 + AH2
(+)-3-hydroxylarreatricin + A + H2O
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enzyme cataylzes the enantio-specific conversion of (+)-larreatricin into (+)-3-hydroxylarreatricin, with the regiochemistry of catalysis being unambiguously established. The corresponding (-)-enantiomer does not serve as a substrate
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3'-hydroxy-larreatricin + O2
3,3'-dihydroxylarreatricin
3-hydroxylation
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3-hydroxy-larreatricin + O2
3,3'-dihydroxylarreatricin
3'-hydroxylation
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the Larrea tridentate PPO gene product acts as a (+)-larreatricin 3'-hydroxylase in vivo
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additional information
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the purified larreatricin-3'-hydroxylase catalyzes a highly enantiospecific reaction
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