1.3.1.16: beta-nitroacrylate reductase
This is an abbreviated version!
For detailed information about beta-nitroacrylate reductase, go to the full flat file.
Word Map on EC 1.3.1.16
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1.3.1.16
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nitroalkenes
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electrophilic
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michael
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4-hydroxynonenal
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hepatocarcinogenesis
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adducts
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nitro-fatty
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spectrometry-based
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hepatocyte
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ischemia-reoxygenation
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unsaturated
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in-gel
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acid-protein
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unbiased
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diethylnitrosamine
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s-transferase
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beta-mercaptoethanol
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nitro-oleic
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beta-oxidation
- 1.3.1.16
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nitroalkenes
-
electrophilic
-
michael
- 4-hydroxynonenal
-
hepatocarcinogenesis
- adducts
-
nitro-fatty
-
spectrometry-based
- hepatocyte
-
ischemia-reoxygenation
- unsaturated
-
in-gel
-
acid-protein
-
unbiased
- diethylnitrosamine
- s-transferase
- beta-mercaptoethanol
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nitro-oleic
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beta-oxidation
Reaction
Synonyms
nitroalkene reductase, nitroalkene reductase-I, nitroalkene reductase-II, prostaglandin reductase-1, PtGR-1, reductase, beta-nitroacrylate
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Substrates Products
Substrates Products on EC 1.3.1.16 - beta-nitroacrylate reductase
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REACTION DIAGRAM
(9E)-9-nitrooctadec-9-enoic acid + NADPH + H+
9-nitrostearic acid + NADP+
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r
(Z)-3-phenyl-2-nitro-2-butene + NADPH
(2R,3R)-3-phenyl-2-nitrobutane + (2S,3R)-3-phenyl-2-nitrobutane + NADP+
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excellent enantioselectivity, moderate diastereoselectivity, mechanism
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?
10-nitrostearic acid + NADP+
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?
10-nitrooctadec-9-enoic acid + NADPH + H+
10-nitrostearic acid + NADP+
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?
3-nitropropanoate + NADP+
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highly specific
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?
3-nitroacrylate + NADPH
3-nitropropanoate + NADP+
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biosynthesis of beta-nitropropionic acid
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?
9-nitrooctadec-9-enoic acid + NADPH + H+
9-nitrostearic acid + NADP+
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?
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enzyme is specific for the reduction of the nitroalkene moiety, yielding saturated non-electrophilic products
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additional information
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no substrates are acrylic acid, crotonic acid, fumaric acid, cinnamic acid, 2-hydroxy-3-nitropropionic acid, shikimic acid, aconitic acid, itaconic acid, pyruvic acid, phosphoenolpyruvate, cytochrome c
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?
additional information
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enzyme is specific for the reduction of the nitroalkene moiety, yielding saturated non-electrophilic products
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-
?