1.3.1.74: 2-alkenal reductase [NAD(P)+]
This is an abbreviated version!
For detailed information about 2-alkenal reductase [NAD(P)+], go to the full flat file.
Word Map on EC 1.3.1.74
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1.3.1.74
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quercitrin
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alpha,beta-unsaturated
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dicumarol
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2-alkenals
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15-ketoprostaglandins
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13-reductase
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dihydrochalcone
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acylfulvenes
- 1.3.1.74
- quercitrin
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alpha,beta-unsaturated
- dicumarol
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2-alkenals
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15-ketoprostaglandins
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13-reductase
- dihydrochalcone
- acylfulvenes
Reaction
Synonyms
2-alkenal reductase, 2AER, AER, alkenal/one oxidoreductase, alkenal/one reductase, AOR, At-AER, At5g16970, AtAER, AtAOR, bifunctional LTB4 12-hydroxydehydrogenase/15-oxo-prostaglandin 13-reductase, CS-670 double-bond reductase, CsAOR, Dbr1, double bond reductase, LTB4 12-HD/PGR, NADPH alkenal/one oxidoreductase, NADPH-dependent 2-alkenal reductase, NADPH-dependent alkenal/one oxidoreductase, ZmAER
ECTree
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Substrates Products
Substrates Products on EC 1.3.1.74 - 2-alkenal reductase [NAD(P)+]
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REACTION DIAGRAM
1-cyclohexene-1-carboxaldehyde + NADPH + H+
cyclohexanecarboxaldehyde + NADP+
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-
-
?
15-deoxy-DELTA12,14-prostaglandin J2 + NADPH + H+
12,13-dihydro-15-deoxy-DELTA12,14-prostaglandin J2 + NADP+
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-
-
-
r
2-[4-[(E)-(2-oxocyclohexylidene)methyl]phenyl]propanoic acid + NADPH
2-[4-[(2-oxocyclohexyl)methyl]phenyl]propanoic acid + NADP+
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2-[4-[(E)-(2-oxocyclohexylidene)methyl]phenyl]propanoic acid is also known as CS-670
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-
?
artemisinic aldehyde + NADPH + H+
dihydroartemisinic aldehyde + NADP+
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at 1.9% of the rate with 2E-nonenal
88% 11S- and 12% 11R-isomer
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?
benzylidine acetone + NAD(P)H
? + NAD(P)+
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reduction of alpha,beta-double bond
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-
?
hexanal + NADP+
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at 12% of the rate with 2E-nonenal
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-
?
4-hydroxynonylaldehyde + NAD(P)+
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-
-
?
4-hydroxy-(2E)-nonenal + NAD(P)H
4-hydroxynonylaldehyde + NAD(P)+
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-
-
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?
illudin M + NADPH
?
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extremly cytotoxic chemotherapeutic agent in cancer therapy, rapid metabolization by the enzyme
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-
?
illudin S + NADPH
?
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extremly cytotoxic chemotherapeutic agent in cancer therapy, rapid metabolization by the enzyme
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?
irofulven + NADPH
?
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less cytotoxic chemotherapeutic agent in cancer therapy, rapid metabolization by the enzyme
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-
?
alk-2-enal + NAD(P)H
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carbon chain length C3-C9 serves as substrates
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-
?
?
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catalyzes the hydrogenation of alpha,beta-unsaturated bonds, but not the reduction of the aldehyde moiety in 2-alkenal molecules
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?
additional information
?
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reduction of the alpha,beta-carbon-carbon double bond to a single bond, broad substrate specificity
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?
additional information
?
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reaction product identification by mass spectrometry
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?
additional information
?
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regio- and stereochemistry of hydride transfer, overview
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?