2.1.1.305: 8-demethyl-8-alpha-L-rhamnosyl tetracenomycin-C 2'-O-methyltransferase
This is an abbreviated version!
For detailed information about 8-demethyl-8-alpha-L-rhamnosyl tetracenomycin-C 2'-O-methyltransferase, go to the full flat file.
Reaction
Synonyms
ElmMI
ECTree
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Substrates Products
Substrates Products on EC 2.1.1.305 - 8-demethyl-8-alpha-L-rhamnosyl tetracenomycin-C 2'-O-methyltransferase
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REACTION DIAGRAM
S-adenosyl-L-methionine + 8-demethyl-8-alpha-L-rhamnosyl-tetracenomycin C
S-adenosyl-L-homocysteine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C
S-adenosyl-L-homocysteine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C
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-
?
S-adenosyl-L-methionine + 8-demethyl-8-alpha-L-rhamnosyl-tetracenomycin C
S-adenosyl-L-homocysteine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C
the enzyme is involved in the biosynthesis of the polyketide elloramycin
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-
?
S-adenosyl-L-methionine + 8-demethyl-8-alpha-L-rhamnosyl-tetracenomycin C
S-adenosyl-L-homocysteine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C
using as biotransformation host strain EPM1 (expressing elmMI) about 24% of the precursor 8-demethyl-8-alpha-L-rhamnosyl tetracenomycin C is converted into 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C. No activity with substrates lacking the hydroxy group at C-2' (8-demethyl-8-alpha-L-oleandrosyl tetracenomycin C or 8-demethyl-8-alpha-L-olivosyl tetracenomycin C)
-
-
?
S-adenosyl-L-methionine + 8-demethyl-8-alpha-L-rhamnosyl-tetracenomycin C
S-adenosyl-L-homocysteine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C
-
-
-
?
S-adenosyl-L-methionine + 8-demethyl-8-alpha-L-rhamnosyl-tetracenomycin C
S-adenosyl-L-homocysteine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C
the enzyme is involved in the biosynthesis of the polyketide elloramycin
-
-
?
S-adenosyl-L-methionine + 8-demethyl-8-alpha-L-rhamnosyl-tetracenomycin C
S-adenosyl-L-homocysteine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C
using as biotransformation host strain EPM1 (expressing elmMI) about 24% of the precursor 8-demethyl-8-alpha-L-rhamnosyl tetracenomycin C is converted into 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin C. No activity with substrates lacking the hydroxy group at C-2' (8-demethyl-8-alpha-L-oleandrosyl tetracenomycin C or 8-demethyl-8-alpha-L-olivosyl tetracenomycin C)
-
-
?