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2.1.1.326: N-acetyldemethylphosphinothricin P-methyltransferase

This is an abbreviated version!
For detailed information about N-acetyldemethylphosphinothricin P-methyltransferase, go to the full flat file.

Reaction

2 S-adenosyl-L-methionine +

N-acetyldemethylphosphinothricin
+
reduced acceptor
=
S-adenosyl-L-homocysteine
+
5'-deoxyadenosine
+
L-methionine
+
N-acetylphosphinothricin
+
oxidized acceptor

Synonyms

BcpD, P-methylase, PhpK, SD_1168

ECTree

     2 Transferases
         2.1 Transferring one-carbon groups
             2.1.1 Methyltransferases
                2.1.1.326 N-acetyldemethylphosphinothricin P-methyltransferase

Natural Substrates Products

Natural Substrates Products on EC 2.1.1.326 - N-acetyldemethylphosphinothricin P-methyltransferase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
2 S-adenosyl-L-methionine + N-acetyldemethylphosphinothricin + reduced acceptor
S-adenosyl-L-homocysteine + 5'-deoxyadenosine + L-methionine + N-acetylphosphinothricin + oxidized acceptor
show the reaction diagram
N-acetyldemethylphosphinothricin i.e. (2S)-2-acetamido-4-phosphinatobutanoate. In vivo the enzyme acts on N-acetyldemethylphosphinothricin-L-alanyl-L-alanine or N-acetyl-demethylphosphinothricin-L-alanyl-L-leucine, the intermediates in the biosynthesis of the tripeptides bialaphos and phosalacine (which inhibit plant and bacterial glutamine synthetases)
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