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2.1.3.12: decarbamoylnovobiocin carbamoyltransferase

This is an abbreviated version!
For detailed information about decarbamoylnovobiocin carbamoyltransferase, go to the full flat file.

Reaction

Carbamoyl phosphate
+
decarbamoylnovobiocin
=
phosphate
+
novobiocin

Synonyms

NovN

ECTree

     2 Transferases
         2.1 Transferring one-carbon groups
             2.1.3 Carboxy- and carbamoyltransferases
                2.1.3.12 decarbamoylnovobiocin carbamoyltransferase

Substrates Products

Substrates Products on EC 2.1.3.12 - decarbamoylnovobiocin carbamoyltransferase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
2 carbamoyl phosphate + N,N'-bis(7-[[(2R,3R,4S,5R)-3,4-dihydroxy-5-methoxy-6,6-dimethyltetrahydro-2H-pyran-2-yl]oxy]-4-hydroxy-8-methyl-2-oxo-2H-chromen-3-yl)-3-methyl-1H-pyrrole-2,4-dicarboxamide
2 phosphate + (3-methyl-1H-pyrrole-2,4-diyl)bis[carbonylimino(4-hydroxy-8-methyl-2-oxo-2H-chromene-3,7-diyl)oxy-(2R,3R,4S,5R)-3-hydroxy-5-methoxy-6,6-dimethyltetrahydro-2H-pyran-2,4-diyl] dicarbamate
show the reaction diagram
-
the tandem action of CouL, CouM, CouP, and NovN generates a biscarbamoyl analogue of the pseudodimer coumermycin A1
-
-
?
carbamoyl phosphate + decarbamoylnovobiocin
phosphate + novobiocin
show the reaction diagram
carbamoyl phosphate + novclobiocin 104
phosphate + ?
show the reaction diagram
-
87% of novclobiocin 104 is converted to the carbamoylated derivative after overnight incubation
-
-
?
carbamoyl phosphate + novclobiocin 105
phosphate + novclobiocin 115
show the reaction diagram
-
-
-
-
?
carbamoyl phosphate + novclobiocin 107
phosphate + novclobiocin 117
show the reaction diagram
-
-
-
-
?
carbamoyl phosphate + novclobiocin 108
phosphate + novclobiocin 118
show the reaction diagram
-
-
-
-
?
carbamoyl phosphate + novclobiocin 283
phosphate + novclobiocin 284
show the reaction diagram
-
-
-
-
?