2.3.1.140: rosmarinate synthase
This is an abbreviated version!
For detailed information about rosmarinate synthase, go to the full flat file.
Word Map on EC 2.3.1.140
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2.3.1.140
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ammonia-lyase
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officinalis
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lamiaceae
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salvia
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melissa
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coleus
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caffeic
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blumei
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phenylpropanoids
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balm
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4-coumarate
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dracocephalum
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shikimic
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4-hydroxyphenyllactate
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lemon
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solenostemon
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lithospermic
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kotschyi
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synthesis
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miltiorrhiza
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boiss
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coumaric
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smras
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verticillata
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phenylpropanoid-derived
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benth
- 2.3.1.140
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ammonia-lyase
- officinalis
- lamiaceae
- salvia
- melissa
-
coleus
-
caffeic
- blumei
-
phenylpropanoids
- balm
- 4-coumarate
-
dracocephalum
-
shikimic
- 4-hydroxyphenyllactate
- lemon
-
solenostemon
-
lithospermic
- kotschyi
- synthesis
- miltiorrhiza
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boiss
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coumaric
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smras
- verticillata
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phenylpropanoid-derived
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benth
Reaction
Synonyms
4-coumaroyl-CoA:4-hydroxyphenyllactic acid 4-coumaroyl transferase, 4-coumaroyl-CoA:hydroxyphenyllactic acid hydroxycinnamoyltransferase, AAT1, AT1, caffeoyl-coenzyme A:3,4-dihydroxyphenyllactic acid caffeoyltransferase, hydroxycinnamoyl-CoA:hydroxyphenyllactate hydroxycinnamoyltransferase, RAS, rosmarinic acid synthase
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 2.3.1.140 - rosmarinate synthase
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REACTION DIAGRAM
4-coumaroyl-CoA + 3-(3,4-dihydroxyphenyl)lactate
CoA + 2-O-(4-coumaroyl)-3-(3,4-dihydroxyphenyl)lactate
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?
4-coumaroyl-CoA + 3-(4-hydroxyphenyl)lactate
CoA + 2-O-(4-coumaroyl)-3-(4-hydroxyphenyl)lactate
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the precursor for rosmarinic acid synthesis via further hydroxylations, overview
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?
caffeoyl-CoA + 3-(4-hydroxyphenyl)lactate
CoA + 2-O-caffeoyl-3-(4-hydroxyphenyl)lactate
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?
CoA + rosmarinate
Coleus scutellarioides
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via intermediate 4-coumaroyl-4'-hydroxyphenyllactic acid
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?
caffeoyl-CoA + 3-(3,4-dihydroxyphenyl)lactate
CoA + rosmarinate
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?
?
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Coleus scutellarioides
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probably 4-coumaroyl-CoA and 4-hydroxyphenyllactate are the substrates used in vivo
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?
additional information
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recombinant LaAAT1 exhibits a broad substrate tolerance accepting (hydroxy)cinnamoyl-CoAs as acyl donors and not only tyramine, tryptamine, phenylethylamine, and anthranilic acid but also shikimic acid and 4-hydroxyphenyllactic acid as acceptors, showing substrate promiscuity
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-
?
additional information
?
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recombinant LaAAT1 exhibits a broad substrate tolerance accepting (hydroxy)cinnamoyl-CoAs as acyl donors and not only tyramine, tryptamine, phenylethylamine, and anthranilic acid but also shikimic acid and 4-hydroxyphenyllactic acid as acceptors, showing substrate promiscuity
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?