2.3.1.166: 2alpha-hydroxytaxane 2-O-benzoyltransferase

This is an abbreviated version!
For detailed information about 2alpha-hydroxytaxane 2-O-benzoyltransferase, go to the full flat file.

Reaction

Synonyms

2-O-benzoyltransferase, benzoyl-CoA:taxane 2alpha-O-benzoyltransferase, benzoyltransferase, taxane 2alpha-O-, mTBT, taxane 2alpha-O-benzoyltransferase, TBT

ECTree

     2 Transferases

         2.3 Acyltransferases

             2.3.1 Transferring groups other than aminoacyl groups

                2.3.1.166 2alpha-hydroxytaxane 2-O-benzoyltransferase

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Results	in table
3	AA Sequence
1	CAS Registry Number
4	Cloned(Commentary)
17	kcat/KM [mM/s]
19	KM Value [mM]
5	Molecular Weight [Da]
1	Natural Substrates/ Products (Substrates)
6	Organism
6	Pathway
1	pH Optimum
1	pH Range
1	pI Value
2	Protein Variants
2	Purification (Commentary)
1	Reaction
1	Reaction Type
6	Reference
2	Source Tissue
24	Substrates and Products (Substrate)
3	Subunits
7	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]
19	Turnover Number [1/s]

Substrates Products

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Substrates Products on EC 2.3.1.166 - 2alpha-hydroxytaxane 2-O-benzoyltransferase

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-1-hydroxy-9-oxo-5,20-epoxytax-11-ene-2,4,7,10,13-pentayl pentaacetate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl (2E)-but-2-enoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 1,3-thiazole-5-carboxylate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 2-fluorobenzoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 2-methylpropanoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 3-fluorobenzoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 3-methylbenzoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 4-chlorobenzoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 4-fluorobenzoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl 4-methylbenzoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl benzoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl butanoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl cyclohexanecarboxylate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl furan-2-carboxylate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl furan-3-carboxylate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl hexanoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl propanoate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl thiophene-2-carboxylate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + (2alpha,5beta,7beta,10beta,13alpha)-4,7,10,13-tetrakis(acetyloxy)-1-hydroxy-9-oxo-5,20-epoxytax-11-en-2-yl thiophene-3-carboxylate

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

benzoyl-CoA + 10-deacetyl-2-debenzoylbaccatin III

CoA + 10-deacetylbaccatin III

Taxus cuspidata

Q9FPW3

-

441598

-

441598

?

benzoyl-CoA + 2-debenzoyl-7,13-diacetylbaccatin III

CoA + 7,13-diacetylbaccatin III

2 entries

benzoyl-CoA + [13-3H]-7,13-O,O-diacetyl-2-O-debenzoylbaccatin III

CoA + ?

Taxus cuspidata

Q9FPW3

-

705244

-

-

?

additional information

?

-

2 entries

benzoyl-CoA + 2-debenzoyl-7,13-diacetylbaccatin III

CoA + 7,13-diacetylbaccatin III

Taxus cuspidata

Q9FPW3

2-debenzoyl-7,13-diacetylbaccatin III is a semisynthetic substrate

441598

-

441598

?

benzoyl-CoA + 2-debenzoyl-7,13-diacetylbaccatin III

CoA + 7,13-diacetylbaccatin III

Taxus x media

-

-

674941

-

-

?

additional information

?

-

Taxus cuspidata

Q9FPW3

enzyme does not benzoylate the 1beta-, 7beta-, 10beta- or 13alpha-hydroxyl groups of 10-deacetylbaccatin III, nor does it benzoylate the 2alpha- or 5alpha-hydroxyl groups of taxa-4(20),11(12)-dien-2alpha,5alpha-diol, acetyl-CoA no cosubstrate

441598

-

-

?

additional information

?

-

Taxus cuspidata

-

enzyme does not benzoylate the 1beta-, 7beta-, 10beta- or 13alpha-hydroxyl groups of 10-deacetylbaccatin III, nor does it benzoylate the 2alpha- or 5alpha-hydroxyl groups of taxa-4(20),11(12)-dien-2alpha,5alpha-diol, acetyl-CoA no cosubstrate

441598

-

-

?