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2.3.1.206: 3,5,7-trioxododecanoyl-CoA synthase

This is an abbreviated version!
For detailed information about 3,5,7-trioxododecanoyl-CoA synthase, go to the full flat file.

Word Map on EC 2.3.1.206

Reaction

3 malonyl-CoA +

hexanoyl-CoA
= 3 CoA +
3,5,7-trioxododecanoyl-CoA
+ 3 CO2

Synonyms

OLA synthase, olivetol synthase, olivetol-forming PKS, OLS, PKS, polyketide synthase, tetraketide synthase, TKS, type III PKS, type III polyketide synthase

ECTree

     2 Transferases
         2.3 Acyltransferases
             2.3.1 Transferring groups other than aminoacyl groups
                2.3.1.206 3,5,7-trioxododecanoyl-CoA synthase

Systematic Name

Systematic Name on EC 2.3.1.206 - 3,5,7-trioxododecanoyl-CoA synthase

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SYSTEMATIC NAME
IUBMB Comments
malonyl-CoA:hexanoyl-CoA malonyltransferase (3,5,7-trioxododecanoyl-CoA-forming)
A polyketide synthase catalysing the first committed step in the cannabinoids biosynthetic pathway of the plant Cannabis sativa. The enzyme was previously thought to also function as a cyclase, but the cyclization is now known to be catalysed by EC 4.4.1.26, olivetolic acid cyclase.