2.3.1.92: sinapoylglucose-malate O-sinapoyltransferase
This is an abbreviated version!
For detailed information about sinapoylglucose-malate O-sinapoyltransferase, go to the full flat file.
Word Map on EC 2.3.1.92
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2.3.1.92
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acyltransferases
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sinapoylmalate
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sinapate
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carboxypeptidases
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phenylpropanoid
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sinapoylated
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short-lived
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brassicaceae
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seedlings
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subfunctionalization
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choline
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transacylation
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ester-dependent
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esterase
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beta-acetal
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neofunctionalization
- 2.3.1.92
- acyltransferases
- sinapoylmalate
- sinapate
- carboxypeptidases
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phenylpropanoid
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sinapoylated
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short-lived
- brassicaceae
- seedlings
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subfunctionalization
- choline
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transacylation
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ester-dependent
- esterase
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beta-acetal
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neofunctionalization
Reaction
Synonyms
1-O-sinapoyl-beta-glucose:L-malate sinapoyltransferase, 1-sinapoylglucose-L-malate sinapoyltransferase, AtSMT, SCPL 1-O-sinapoyl-beta-glucose:L-malate sinapoyltransferase, SCPL SMT, serine carboxypeptidase-like 1-O-sinapoyl-beta-glucose:L-malate sinapoyltransferase, sinapoylglucose:malate sinapoyltransferase, SMT
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Substrates Products
Substrates Products on EC 2.3.1.92 - sinapoylglucose-malate O-sinapoyltransferase
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REACTION DIAGRAM
1,2-di-O-sinapoyl-beta-D-glucose + L-malate
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at 26% the rate of the reaction with 1-O-sinapoylglucose
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-
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1-O-(4-coumaroyl)-beta-D-glucose + L-malate
D-glucose + 4-coumaroyl-L-malate
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poor substrate
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-
?
1-O-caffeoyl-beta-D-glucose + L-malate
D-glucose + caffeoyl-L-malate
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at 45% the rate of the reaction with 1-O-sinapoylglucose
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-
?
1-O-feruloyl-beta-D-glucose + L-malate
D-glucose + feruloyl-L-malate
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at 85% the rate of the reaction with 1-O-sinapoylglucose
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-
?
1-O-sinapoyl-beta-D-glucose
1,2-di-O-sinapoyl-beta-D-glucose + D-glucose
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in the absence or weak binding of L-malate at pH 8.0
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-
?
1-O-sinapoyl-beta-D-glucose + H2O
sinapic acid + D-glucose
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minor hydrolytic activity under standard conditions, strongly increasing in the absence of L-malate and at pH 8.0
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-
?
D-glucose + sinapoyl-L-malate
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-
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?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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-
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?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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-
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?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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-
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?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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key step in overall conversion of seed constituent sinapine to sinapoylmalate
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-
?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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-
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?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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-
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?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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-
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ir
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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no donor is sinapic acid
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?
1-O-sinapoyl-beta-D-glucose + L-malate
D-glucose + sinapoyl-L-malate
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is involved in phenylpropanoid depside formation
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-
?
sinapoyl-L-malate + D-glucose
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-
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?
1-O-sinapoyl-beta-D-glucose + L-malate
sinapoyl-L-malate + D-glucose
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standard conditions, pH 6.0
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?