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2.4.1.238: delphinidin 3,5-di-O-glucoside 3'-O-glucosyltransferase

This is an abbreviated version!
For detailed information about delphinidin 3,5-di-O-glucoside 3'-O-glucosyltransferase, go to the full flat file.

Reaction

UDP-alpha-D-glucose
+
delphinidin 3,5-di-O-beta-D-glucoside
=
UDP
+
delphinidin 3,3',5-tri-O-beta-D-glucoside

Synonyms

3'GT, anthocyanin 3'-O-beta-D-glucosyltransferase, UDP-glucose:anthocyanin 3'-O-glucosyltransferase

ECTree

     2 Transferases
         2.4 Glycosyltransferases
             2.4.1 Hexosyltransferases
                2.4.1.238 delphinidin 3,5-di-O-glucoside 3'-O-glucosyltransferase

Substrates Products

Substrates Products on EC 2.4.1.238 - delphinidin 3,5-di-O-glucoside 3'-O-glucosyltransferase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
UDP-alpha-D-glucose + delphinidin 3-O-glucosyl-5-O-(6-O-caffeoylglucoside)
UDP + delphinidin 3-O,3'-O-di-beta-D-glucosyl-5-O-(6-O-caffeoyl-beta-D-glucoside)
show the reaction diagram
in vitro, 50.9% of the activity with delphinidin 3,5-diglucoside
-
-
?
UDP-glucose + an anthocyanidin
UDP + an anthocyanidin 3'-O-beta-D-glucoside
show the reaction diagram
strict substrate specificity, 3'GT specifically glucosylates the 3'-hydroxy group of delphinidin-type anthocyanins containing glucose groups at the 3 and 5 positions and specifically uses UDP-glucose as the sugar donor, 3’GT strictly requires three hydroxy groups on the B-ring for its substrates
-
-
?
UDP-glucose + delphinidin
UDP + delphinidin 3'-glucoside
show the reaction diagram
poor substrate, 3.3% of the activity with delphinidin 3,5-diglucoside
-
-
?
UDP-glucose + delphinidin 3,5-di-O-beta-D-glucoside
UDP + delphinidin 3,5,7-tri-O-beta-D-glucoside
show the reaction diagram
3'GT glucosylates the 3'-hydroxy group of delphinidin 3,5-diglucoside, 2fold higher activity than with delphinidin 3-O-glucosyl-5-O-(6-O-caffeoylglucoside) as substrate
-
-
?
UDP-glucose + delphinidin 3-glucoside
UDP + delphinidin 3,3'-diglucoside
show the reaction diagram
poor substrate, 2.9% of the activity with delphinidin 3,5-diglucoside
-
-
?
additional information
?
-