2.5.1.110: 12alpha,13alpha-dihydroxyfumitremorgin C prenyltransferase
This is an abbreviated version!
For detailed information about 12alpha,13alpha-dihydroxyfumitremorgin C prenyltransferase, go to the full flat file.
Reaction
Synonyms
ftmH, FtmPT2, ftmPTS
ECTree
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Substrates Products
Substrates Products on EC 2.5.1.110 - 12alpha,13alpha-dihydroxyfumitremorgin C prenyltransferase
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REACTION DIAGRAM
dimethylallyl diphosphate + 12alpha,13alpha-dihydroxyfumitremorgin C
diphosphate + fumitremorgin B
dimethylallyl diphosphate + fumitremorgin C
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relative activity of 10% compared to 12,13-dihydroxyfumitremorgin C
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diphosphate + fumitremorgin B
the enzyme is involved in the biosynthetic pathways of several indole alkaloids such as fumitremorgins and verruculogen
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dimethylallyl diphosphate + 12alpha,13alpha-dihydroxyfumitremorgin C
diphosphate + fumitremorgin B
the enzyme is specific for dimethylallyl diphosphate as prenyl donor, no activity with geranyl diphosphate. Relatively high specificity towards the aromatic substrate, it is extremely regiospecific
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no activity with brevianamide F, tryprostatin A or B
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additional information
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no activity with brevianamide F, tryprostatin A or B
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