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2.5.1.111: 4-hydroxyphenylpyruvate 3-dimethylallyltransferase

This is an abbreviated version!
For detailed information about 4-hydroxyphenylpyruvate 3-dimethylallyltransferase, go to the full flat file.

Word Map on EC 2.5.1.111

Reaction

dimethylallyl diphosphate
+
4-hydroxyphenylpyruvate
=
diphosphate
+
3-dimethylallyl-4-hydroxyphenylpyruvate

Synonyms

4HPP dimethylallyltransferase, apT, aromatic prenyltransferase, CloQ, FamD1, isoprenyl transferase, NovQ

ECTree

     2 Transferases
         2.5 Transferring alkyl or aryl groups, other than methyl groups
             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
                2.5.1.111 4-hydroxyphenylpyruvate 3-dimethylallyltransferase

Substrates Products

Substrates Products on EC 2.5.1.111 - 4-hydroxyphenylpyruvate 3-dimethylallyltransferase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
dimethylallyl diphosphate + (2Z)-3-(1H-indol-3-yl)prop-2-enenitrile
diphosphate + (2E)-3-[2-(3-methylbut-2-en-1-yl)-1H-indol-3-yl]prop-2-enenitrile + (2E)-3-[2-(3-methylbut-2-en-1-yl)-3H-indol-3-yl]prop-2-enenitrile
show the reaction diagram
dimethylallyl diphosphate + 1,6-dihydroxynaphthalene
diphosphate + 1-O-dimethylallyl-1,6-dihydroxynaphthalene
show the reaction diagram
dimethylallyl diphosphate + 2,7-dihydroxynaphthalene
diphosphate + 1-dimethylallyl-2,7-dihydroxynaphthalene
show the reaction diagram
dimethylallyl diphosphate + 3'-hydroxydaidzein
?
show the reaction diagram
2% conversion
-
-
?
dimethylallyl diphosphate + 4'-hydroxy-6-methoxyflavone
?
show the reaction diagram
1% conversion
-
-
?
dimethylallyl diphosphate + 4'-hydroxy-7-methoxyflavone
?
show the reaction diagram
2% conversion
-
-
?
dimethylallyl diphosphate + 4'-hydroxy-7-methoxyflavone
diphosphate + 2-[4-hydroxy-3-(3-methylbut-2-en-1-yl)phenyl]-7-methoxy-4H-chromen-4-one + 7-methoxy-2-[4-[(3-methylbut-2-en-1-yl)oxy]phenyl]-4H-chromen-4-one
show the reaction diagram
2% conversion
-
-
?
dimethylallyl diphosphate + 4-coumarate
diphosphate + 4-O-dimethylallylcoumarate
show the reaction diagram
dimethylallyl diphosphate + 4-hydroxyphenylpyruvate
diphosphate + 3-dimethylallyl-4-hydroxyphenylpyruvate
show the reaction diagram
dimethylallyl diphosphate + 7,4'-dihydroxyflavone
?
show the reaction diagram
4% conversion
-
-
?
dimethylallyl diphosphate + apigenin
diphosphate + 3'-C-dimethylallyl apigenin
show the reaction diagram
7.6% yield
-
-
?
dimethylallyl diphosphate + caffeate
diphosphate + 3-O,4-O-bis-(dimethylallyl)caffeate
show the reaction diagram
20% yield
-
-
?
dimethylallyl diphosphate + caffeate
diphosphate + 3-O-(dimethylallyl)caffeate
show the reaction diagram
17.3% yield
-
-
?
dimethylallyl diphosphate + caffeate
diphosphate + 4-O-(dimethylallyl)caffeate
show the reaction diagram
26.1% yield
-
-
?
dimethylallyl diphosphate + coumestrol
?
show the reaction diagram
1% conversion
-
-
?
dimethylallyl diphosphate + daidzein
?
show the reaction diagram
less than 1% conversion
-
-
?
dimethylallyl diphosphate + equol
?
show the reaction diagram
8% conversion
-
-
?
dimethylallyl diphosphate + equol
diphosphate + 3-[4-hydroxy-3-(3-methylbut-2-en-1-yl)phenyl]-3,4-dihydro-2H-chromen-7-ol + 3-(4-hydroxyphenyl)-6-(3-methylbut-2-en-1-yl)-3,4-dihydro-2H-chromen-7-ol
show the reaction diagram
2% conversion
-
-
?
dimethylallyl diphosphate + genistein
?
show the reaction diagram
less than 1% conversion
-
-
?
dimethylallyl diphosphate + hapalindole U
diphosphate + ambiguine H
show the reaction diagram
dimethylallyl diphosphate + luteolin
?
show the reaction diagram
3% conversion
-
-
?
dimethylallyl diphosphate + menadione hydroquinol
diphosphate + vitamin MK1
show the reaction diagram
dimethylallyl diphosphate + naringenin
diphosphate + 3'-C-dimethylallyl naringenin
show the reaction diagram
87.2% yield
-
-
?
dimethylallyl diphosphate + naringenin
diphosphate + 4'-O-dimethylallyl naringenin
show the reaction diagram
11.1% yield
-
-
?
dimethylallyl diphosphate + resveratrol
?
show the reaction diagram
2% conversion
-
-
?
dimethylallyl diphosphate + resveratrol
diphosphate + 3'-dimethylallyl resveratrol
show the reaction diagram
12.3% yield
-
-
?
geranyl diphosphate + (2Z)-3-(1H-indol-3-yl)prop-2-enenitrile
diphosphate + (2Z)-3-(2-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-1H-indol-3-yl)prop-2-enenitrile + (2E)-3-(2-[(2E)-3,7-dimethylocta-2,6-dien-1-yl]-3H-indol-3-yl)prop-2-enenitrile
show the reaction diagram
additional information
?
-