2.5.1.124: 6-linalyl-2-O,3-dimethylflaviolin synthase
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Reaction
Synonyms
Fur7
ECTree
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Systematic Name
Systematic Name on EC 2.5.1.124 - 6-linalyl-2-O,3-dimethylflaviolin synthase
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geranyl diphosphate:2-O-methyl-3-methylflaviolin geranyltransferase (6-(3,7-dimethylocta-1,6-dien-3-yl)-5,7-dihydroxy-2-methoxy-3-methylnaphthalene-1,4-dione-forming)
The enzyme is involved in biosynthesis of the polyketide-isoprenoid furaquinocin D in the bacterium Streptomyces sp. KO-3988. It catalyses the transfer of a geranyl group to 2-O,3-dimethylflaviolin to yield 6-linalyl-2-O,3-dimethylflaviolin and 7-O-geranyl-2-O,3-dimethylflaviolin (cf. EC 2.5.1.125, 7-geranyloxy-5-hydroxy-2-methoxy-3-methylnaphthalene-1,4-dione synthase) in a 10:1 ratio.