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2.5.1.34: 4-dimethylallyltryptophan synthase

This is an abbreviated version!
For detailed information about 4-dimethylallyltryptophan synthase, go to the full flat file.

Word Map on EC 2.5.1.34

Reaction

dimethylallyl diphosphate
+
L-tryptophan
=
diphosphate
 +
4-(3-methylbut-2-enyl)-L-tryptophan

Synonyms

4-(gamma,gamma-dimethylallyl)tryptophan synthase, 4-dimethylallyltryptophan synthase, 4-DMATS, 7-dimethylallyltryptophan synthase, 7-DMATS, C4-prenyltransferase, dimethylallyl-tryptophan synthase, dimethylallylpyrophosphate:L-tryptophan dimethylallyltransferase, dimethylallylpyrophosphate:tryptophan dimethylallyl transferase, dimethylallylpyrophosphate:tryptophan dimethylallyltransferase, dimethylallyltransferase, tryptophan, dimethylallyltryptophan synthase, dimethylallyltryptophan synthetase, DMAT synthase, DMAT synthetase, DMATS, DmaW, DmaW2, FgaPT2, IfgA, MaPT, Proq05g069320, tryptophan C4-prenyltransferase, tryptophan C4-prenyltransferase FgaPT2, tryptophan C4-PT

ECTree

     2 Transferases
         2.5 Transferring alkyl or aryl groups, other than methyl groups
             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
                2.5.1.34 4-dimethylallyltryptophan synthase

KM Value

KM Value on EC 2.5.1.34 - 4-dimethylallyltryptophan synthase

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KM VALUE [mM]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
0.056
2-pentenyl diphosphate
-
37°C, pH not specified in the publication
0.017
4-amino-L-tryptophan
pH 8.0, 30°C, recombinant His-tagged 4-DMATS
0.25
4-methoxy-L-tryptophan
pH 8.0, 30°C, recombinant His-tagged 4-DMATS
0.089
4-methyl-L-tryptophan
pH 8.0, 30°C, recombinant His-tagged 4-DMATS
0.3031 - 0.509
5-hydroxy-L-tryptophan
0.039 - 0.416
5-methyl-DL-tryptophan
0.103
6-methyl-DL-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.129
7-methyl-DL-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.35
alpha-methyl-DL-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.032
ardeemin fumiquinazoline
pH 7.5, 37°C, wild-type enzyme
0.4
cyclo-D-Trp-L-Tyr
mutant enzyme R244L, pH 7.5, 37°C
0.46
cyclo-L-Trp-D-Pro
mutant enzyme R244L, pH 7.5, 37°C
0.74
cyclo-L-Trp-Gly
mutant enzyme R244L, pH 7.5, 37°C
0.42
cyclo-L-Trp-L-Leu
mutant enzyme R244Y, pH 7.5, 37°C
0.17
cyclo-L-Trp-L-Phe
mutant enzyme R244Y, pH 7.5, 37°C
0.28
cyclo-L-Trp-L-Pro
mutant enzyme R244L, pH 7.5, 37°C
0.22
cyclo-L-Trp-L-Trp
mutant enzyme R244M, pH 7.5, 37°C
0.439
cyclo-L-tryptophan-glycine
-
-
0.14
cyclo-L-tryptophan-L-leucine
-
-
0.536
cyclo-L-tryptophan-L-proline
-
-
0.326
cyclo-L-tryptophan-L-tryptophan
-
-
0.354
cyclo-L-tryptophan-L-tyrosine
-
-
0.055
dia-ardeemin fumiquinazoline
pH 7.5, 37°C, wild-type enzyme
0.004 - 0.2
dimethylallyl diphosphate
0.011
ent-ardeemin fumiquinazoline
pH 7.5, 37°C, wild-type enzyme
0.558
Indole-3-propionic acid
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.081
L-abrine
pH 7.5, 37°C
0.242
L-beta-homotryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.9
L-m-tyrosine
pH 7.5, 37°C, recombinant enzyme
0.47
L-o-tyrosine
pH 7.5, 37°C, recombinant enzyme
0.0067 - 0.238
L-tryptophan
0.186 - 2.876
L-tryptophan methyl ester
0.04
methylallyl diphosphate
-
37°C, pH not specified in the publication
0.13
N-methyl-L-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.106
Nalpha-methyl-L-tryptophan
pH 7.4, 30°C
0.009
tryptophan
-
in presence of Ca2+
additional information
additional information
-