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2.5.1.34: 4-dimethylallyltryptophan synthase

This is an abbreviated version!
For detailed information about 4-dimethylallyltryptophan synthase, go to the full flat file.

Word Map on EC 2.5.1.34

Reaction

dimethylallyl diphosphate
+
L-tryptophan
=
diphosphate
 +
4-(3-methylbut-2-enyl)-L-tryptophan

Synonyms

4-(gamma,gamma-dimethylallyl)tryptophan synthase, 4-dimethylallyltryptophan synthase, 4-DMATS, 7-dimethylallyltryptophan synthase, 7-DMATS, C4-prenyltransferase, dimethylallyl-tryptophan synthase, dimethylallylpyrophosphate:L-tryptophan dimethylallyltransferase, dimethylallylpyrophosphate:tryptophan dimethylallyl transferase, dimethylallylpyrophosphate:tryptophan dimethylallyltransferase, dimethylallyltransferase, tryptophan, dimethylallyltryptophan synthase, dimethylallyltryptophan synthetase, DMAT synthase, DMAT synthetase, DMATS, DmaW, DmaW2, FgaPT2, IfgA, MaPT, Proq05g069320, tryptophan C4-prenyltransferase, tryptophan C4-prenyltransferase FgaPT2, tryptophan C4-PT

ECTree

     2 Transferases
         2.5 Transferring alkyl or aryl groups, other than methyl groups
             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
                2.5.1.34 4-dimethylallyltryptophan synthase

Turnover Number

Turnover Number on EC 2.5.1.34 - 4-dimethylallyltryptophan synthase

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TURNOVER NUMBER [1/s]
SUBSTRATE
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
IMAGE
0.011
2-pentenyl diphosphate
-
37°C, pH not specified in the publication
0.42
4-amino-L-tryptophan
pH 8.0, 30°C, recombinant His-tagged 4-DMATS
1.3
4-methoxy-L-tryptophan
pH 8.0, 30°C, recombinant His-tagged 4-DMATS
0.75
4-methyl-L-tryptophan
pH 8.0, 30°C, recombinant His-tagged 4-DMATS
0.165 - 0.56
5-hydroxy-L-tryptophan
0.0683 - 0.125
5-methyl-DL-tryptophan
0.0533
6-methyl-DL-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.1267
7-methyl-DL-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.1033
alpha-methyl-DL-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.009
ardeemin fumiquinazoline
pH 7.5, 37°C, wild-type enzyme
0.038
cyclo-D-Trp-L-Tyr
mutant enzyme R244L, pH 7.5, 37°C
0.107
cyclo-L-Trp-D-Pro
mutant enzyme R244L, pH 7.5, 37°C
0.02
cyclo-L-Trp-Gly
mutant enzyme R244L, pH 7.5, 37°C
0.093
cyclo-L-Trp-L-Leu
mutant enzyme R244Y, pH 7.5, 37°C
0.032
cyclo-L-Trp-L-Phe
mutant enzyme R244Y, pH 7.5, 37°C
0.087
cyclo-L-Trp-L-Pro
mutant enzyme R244L, pH 7.5, 37°C
0.032
cyclo-L-Trp-L-Trp
mutant enzyme R244M, pH 7.5, 37°C
0.00106
cyclo-L-tryptophan-glycine
-
-
0.0017
cyclo-L-tryptophan-L-leucine
-
-
0.00113
cyclo-L-tryptophan-L-proline
-
-
0.0021
cyclo-L-tryptophan-L-tryptophan
-
-
0.0017
cyclo-L-tryptophan-L-tyrosine
-
-
0.009
dia-ardeemin fumiquinazoline
pH 7.5, 37°C, wild-type enzyme
0.001 - 0.917
dimethylallyl diphosphate
0.0016
ent-ardeemin fumiquinazoline
pH 7.5, 37°C, wild-type enzyme
0.2683
Indole-3-propionic acid
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.043
L-abrine
pH 7.5, 37°C
0.3767
L-beta-homotryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
0.0065
L-m-tyrosine
pH 7.5, 37°C, recombinant enzyme
0.29
L-o-tyrosine
pH 7.5, 37°C, recombinant enzyme
0.001 - 60
L-tryptophan
0.117 - 0.1367
L-tryptophan methyl ester
0.009
methylallyl diphosphate
-
37°C, pH not specified in the publication
0.252
N-methyl-L-tryptophan
-
in 50 mM Tris/HCl (pH 7.5) with 5 mM CaCl2
1.06
Nalpha-methyl-L-tryptophan
pH 7.4, 30°C