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2.5.1.67: chrysanthemyl diphosphate synthase

This is an abbreviated version!
For detailed information about chrysanthemyl diphosphate synthase, go to the full flat file.

Word Map on EC 2.5.1.67

Reaction

2 dimethylallyl diphosphate =

diphosphate
+
chrysanthemyl diphosphate

Synonyms

CDS, CDS_CCI2, chrysanthemol synthase, chrysanthemyl diphosphate synthase, CPP, CPP synthase, CPPase, FDS-5

ECTree

     2 Transferases
         2.5 Transferring alkyl or aryl groups, other than methyl groups
             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
                2.5.1.67 chrysanthemyl diphosphate synthase

Natural Substrates Products

Natural Substrates Products on EC 2.5.1.67 - chrysanthemyl diphosphate synthase

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NATURAL SUBSTRATE
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
2 dimethylallyl diphosphate
diphosphate + chrysanthemyl diphosphate
show the reaction diagram
2 dimethylallyl diphosphate
diphosphate + lavandulyl diphosphate
show the reaction diagram
reaction of EC 2.5.1.69, chrysanthemyl diphosphate synthase is an inefficient promiscuous enzyme, which synthesizes the irregular monoterpenes chrysanthemyl diphosphate (CPP), lavandulyl diphosphate (LPP), and trace quantities of maconelliyl diphosphate (MPP) from two molecules of DMAPP, and couples IPP to DMAPP to give GPP
-
-
?
6 dimethylallyl diphosphate
(R)-lavandulyl diphosphate + (R)-maconelliyl diphosphate + (1R,3R)-chyrsanthemyl diphosphate + 3 diphosphate
show the reaction diagram
-
non-head-to-tail alcohols after incubation of dimethylallyl diphosphate with CPP synthase followed by hydrolysis with alkaline phosphatase
-
?
dimethylallyl diphosphate + isopentenyl diphosphate
diphosphate + geranyl diphosphate
show the reaction diagram
reaction of EC 2.5.1.1, chrysanthemyl diphosphate synthase is an inefficient promiscuous enzyme, which synthesizes the irregular monoterpenes chrysanthemyl diphosphate (CPP), lavandulyl diphosphate (LPP), and trace quantities of maconelliyl diphosphate (MPP) from two molecules of DMAPP, and couples IPP to DMAPP to give GPP
-
-
?
additional information
?
-