2.5.1.94: adenosyl-chloride synthase
This is an abbreviated version!
For detailed information about adenosyl-chloride synthase, go to the full flat file.
Word Map on EC 2.5.1.94
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2.5.1.94
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chlorinate
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halogen
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fluorinase
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polyketide
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halogenase
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tropica
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salinispora
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halide
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cattleya
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salinosporamide
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fluorination
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synthesis
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flavin-dependent
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cl
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fluoride
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congener
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desolvation
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chemoenzymatic
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non-ribosomal
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flavin
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fad-dependent
- 2.5.1.94
-
chlorinate
-
halogen
-
fluorinase
- polyketide
- halogenase
- tropica
-
salinispora
- halide
- cattleya
-
salinosporamide
-
fluorination
- synthesis
-
flavin-dependent
- cl
- fluoride
-
congener
-
desolvation
-
chemoenzymatic
-
non-ribosomal
- flavin
-
fad-dependent
Reaction
Synonyms
5'-chloro-5'-deoxyadenosine synthase, AclH, chlorinase, Cla1, ClA2, S-adenosyl-L-methionine-dependent chlorinase, SalL, SAM-dependent chlorinase
ECTree
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General Information
General Information on EC 2.5.1.94 - adenosyl-chloride synthase
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malfunction
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a chlorinase knockout mutated strain of Salinispora tropica is able to biosynthesis the fluorinated analogue of salinosporamide A, when the medium was supplemented with 5-deoxy-5-fluoroadenosine
metabolism
physiological function
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the enzyme catalyzes chlorination, the last step in the aspirochlorine pathway, modeling of the aspirochlorine biosynthesis involving an unusual Phe to Gly conversion, overview
metabolism
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the enzyme is responsible for salinosporamide-A biosynthesis
metabolism
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the enzyme catalyzes chlorination, the last step in the aspirochlorine pathway, modeling of the aspirochlorine biosynthesis involving an unusual Phe to Gly conversion, overview
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SalL functions in an orthogonal manner to biological chlorination reactions to initiate the biosynthesis of a new halogenated polyketide synthase building block
physiological function
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key role of AclH as a chlorinase in the aspirochlorine biosynthesis. Aspirochlorine, or antibiotic A30641, is an epidithiodiketopiperazine toxin distinctive antifungal properties due to selective inhibition of protein biosynthesis produced from Aspergillus oryzae
physiological function
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key role of AclH as a chlorinase in the aspirochlorine biosynthesis. Aspirochlorine, or antibiotic A30641, is an epidithiodiketopiperazine toxin distinctive antifungal properties due to selective inhibition of protein biosynthesis produced from Aspergillus oryzae
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