2.7.1.66: undecaprenol kinase
This is an abbreviated version!
For detailed information about undecaprenol kinase, go to the full flat file.
Reaction
Synonyms
C55-isoprenoid alcohol kinase, C55-isoprenoid alcohol phosphokinase, C55-isoprenyl alcohol phosphokinase, DGKA, isoprenoid alcohol kinase, isoprenoid alcohol phosphokinase, isoprenoid-alcohol kinase, kinase (phosphorylating), isoprenoid alcohol, kinase, isoprenoid alcohol (phosphorylating), polyisoprenol kinase, UDPK, undecaprenyl phosphokinase, UOH kinase, Upk
ECTree
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Substrates Products
Substrates Products on EC 2.7.1.66 - undecaprenol kinase
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REACTION DIAGRAM
ATP + (Z,E,E)-geranylgeraniol
ADP + (Z,E,E)-geranylgeraniyl phosphate
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5% of the activity with undecaprenol
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-
?
ATP + C55-isoprenoid alcohol
ADP + C55-isoprenoid alcohol monophosphate
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-
-
-
?
ADP + (E,E,E)-geranylgeraniyl phosphate
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28% of the activity with ATP
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-
?
ATP + (E,E,E)-geranylgeraniol
ADP + (E,E,E)-geranylgeraniyl phosphate
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5%, of the activity with ATP
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-
?
ADP + dolichyl phosphate
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13% of the activity with undecaprenol
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-
?
ATP + dolichol
ADP + dolichyl phosphate
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26% of the activity with undecaprenol
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-
?
ADP + solanesyl phosphate
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about 85% of the activity with undecaprenol
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-
?
ADP + undecaprenyl monophosphate
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best substrate
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?
ATP + undecaprenol
ADP + undecaprenyl monophosphate
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best substrate
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-
?
ATP + undecaprenol
ADP + undecaprenyl monophosphate
56% turnover
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-
?
ATP + undecaprenol
ADP + undecaprenyl phosphate
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-
-
?
ATP + undecaprenol
ADP + undecaprenyl phosphate
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enzyme is involved in biofilm and smegma formation. Absence of Upk influences colony morphology and bacitracin resistance
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?
ATP + undecaprenol
ADP + undecaprenyl phosphate
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?
?
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the diacylglycerol kinase of Escherichia coli shows very low undecaprenol kinase, a true undecaprenol kinase is not found in Escherichia coli
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additional information
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product of the reaction is a substrate for the synthesis of lipid intermediates in peptidoglycan synthesis
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additional information
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the product of the reaction, C55-isoprenoid alcohol monophosphate functions in the biosynthesis of bacterial peptidoglycan and lipopolysaccharides
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additional information
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the enzyme predominantly affects growth of the cells under stress conditions
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additional information
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the enzyme is also a Mg-ADP-dependent undecaprenyl phosphate phosphatase catalyzing the hydrolysis of C55P to C55OH and a free inorganic phosphate
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