Information on EC 1.1.1.296 - dihydrocarveol dehydrogenase

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The expected taxonomic range for this enzyme is: Rhodococcus erythropolis

EC NUMBER
COMMENTARY hide
1.1.1.296
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RECOMMENDED NAME
GeneOntology No.
dihydrocarveol dehydrogenase
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REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
menth-8-en-2-ol + NAD+ = menth-8-en-2-one + NADH + H+
show the reaction diagram
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PATHWAY
BRENDA Link
KEGG Link
MetaCyc Link
(4R)-carveol and (4R)-dihydrocarveol degradation
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(4S)-carveol and (4S)-dihydrocarveol degradation
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Limonene and pinene degradation
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SYSTEMATIC NAME
IUBMB Comments
menth-8-en-2-ol:NAD+ oxidoreductase
This enzyme from the Gram-positive bacterium Rhodococcus erythropolis DCL14 forms part of the carveol and dihydrocarveol degradation pathway. The enzyme accepts all eight stereoisomers of menth-8-en-2-ol as substrate, although some isomers are converted faster than others. The preferred substrates are (+)-neoisodihydrocarveol, (+)-isodihydrocarveol, (+)-dihydrocarveol and (-)-isodihydrocarveol.
CAS REGISTRY NUMBER
COMMENTARY hide
287179-19-5
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ORGANISM
COMMENTARY hide
LITERATURE
UNIPROT
SEQUENCE DB
SOURCE
NAD+-dependent dihydrocarveol dehydrogenase activity is high in carveol- and dihydrocarveol grown cells; strain DCL14
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Manually annotated by BRENDA team
NAD+-dependent dihydrocarveol dehydrogenase activity is high in carveol- and dihydrocarveol grown cells; strain DCL14
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Manually annotated by BRENDA team
SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(1R,2R,4R)-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
show the reaction diagram
(1R,2S,4R)-neo-dihydrocarveol + NAD+
(1R,4R)-dihydrocarvone + NADH + H+
show the reaction diagram
(1S,2R,4R)-neoisodihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
show the reaction diagram
(1S,2S,4R)-iso-dihydrocarveol + NAD+
(1S,4R)-iso-dihydrocarvone + NADH + H+
show the reaction diagram