Literature summary for 1.10.3.1 extracted from

Sarkar, N.; Harms, K.; Frontera, A.; Chattopadhyay, S.
Importance of C-H...pi interactions in stabilizing the syn/anti arrangement of pendant alkoxy side arms in two manganese(IV) Schiff base complexes Exploration of catechol oxidase and phenoxazinone synthase like actIVities (2017), New J. Chem., 41, 8053-8065 .

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Crystallization (Commentary)

Crystallization (Comment)	Organism
complexes [Mn(HL1)(L1)(NCS)]n and [Mn(HL2)2(OH)Cl]	synthetic construct

Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
3,5-di-tert-butylcatechol + O2	-	synthetic construct	3,5-di-tert-butyl-o-benzoquinone + H2O	-	?

General Information

General Information	Comment	Organism
metabolism	octahedral manganese(IV) complexes [Mn(HL1)(L1)(NCS)]n and [Mn(HL2)2(OH)Cl] (where HL1 = 1-(5-hydroxy-3-oxapentyliminomethyl)-3-ethoxyphenol and HL2 = 1-(5-hydroxy-3-oxapentyliminomethyl)-4-chlorophenol) exhibit catechol oxidase and phenoxazinone synthase like activities. Unconventional C-H...pi(SCN) interactions play a key role in stabilizing the syn arrangement of the ligand pending arms in [Mn(HL1)(L1)(NCS)]n, whereas conventional C-H...pi(phe) interactions favour the anti arrangements in [Mn(HL2)2(OH)Cl]	synthetic construct

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Release 2023.1 (January 2023)