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Literature summary for 1.11.1.18 extracted from
- Characterization of vanadium bromoperoxidase from Macrocystis and Fucus: reactivity of vanadium bromoperoxidase toward acyl and alkyl peroxides and bromination of amines (1990), Biochemistry, 29, 7974-7981.
Inhibitors
| Inhibitors | Comment | Organism | Structure |
|---|---|---|---|
| Br- | - |
Fucus distichus |  |
Metals/Ions
| Metals/Ions | Comment | Organism | Structure |
|---|---|---|---|
| Vanadium | contains 0.3 vanadium ions per subunit | Fucus distichus | |
| Vanadium | contains 0.38 vanadium ions per subunit | Macrocystis pyrifera | |
Molecular Weight [Da]
| Molecular Weight [Da] | Molecular Weight Maximum [Da] | Comment | Organism |
|---|---|---|---|
| 65000 | - |
x * 65000, SDS-PAGE | Fucus distichus |
| 74000 | - |
x * 74000, SDS-PAGE | Macrocystis pyrifera |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Fucus distichus | - |
- |
- |
| Macrocystis pyrifera | - |
- |
- |
Purification (Commentary)
| Purification (Comment) | Organism |
|---|---|
- |
Macrocystis pyrifera |
- |
Fucus distichus |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| Br- + H2O2 + 1,1-dimethyl-4-chloro-3,5-cyclohexanedione | i.e. monochlorodimedone | Macrocystis pyrifera | ? | - |
? | |
| Br- + H2O2 + 1,1-dimethyl-4-chloro-3,5-cyclohexanedione | i.e. monochlorodimedone | Fucus distichus | ? | - |
? | |
| Capso + Br- + peracetic acid | - |
Macrocystis pyrifera | ? | - |
? | |
| Capso + Br- + peracetic acid | - |
Fucus distichus | ? | - |
? | |
| cytosine + Br- + peracetic acid | - |
Macrocystis pyrifera | 5-bromocytosine + ? | - |
? | |
| cytosine + Br- + peracetic acid | - |
Fucus distichus | 5-bromocytosine + ? | - |
? | |
| Hepes + Br- + peracetic acid | - |
Macrocystis pyrifera | ? | - |
? | |
| Hepes + Br- + peracetic acid | - |
Fucus distichus | ? | - |
? | |
| Mops + Br- + peracetic acid | - |
Macrocystis pyrifera | 5-bromocytosine + ? | - |
? | |
| Mops + Br- + peracetic acid | - |
Fucus distichus | 5-bromocytosine + ? | - |
? | |
| additional information | the alkyl hydroperoxides ethyl hydroperoxide, cuminyl hydroperoxide, and tert-butyl hydroperoxide do not support bromination of dioxygen formation catalyzed by V-BrPO | Macrocystis pyrifera | ? | - |
? | |
| additional information | the alkyl hydroperoxides ethyl hydroperoxide, cuminyl hydroperoxide, and tert-butyl hydroperoxide do not support bromination of dioxygen formation catalyzed by V-BrPO | Fucus distichus | ? | - |
? | |
| taurine + Br- + peracetic acid | - |
Macrocystis pyrifera | bromotaurine + ? | - |
? | |
| taurine + Br- + peracetic acid | - |
Fucus distichus | bromotaurine + ? | - |
? | |
| Tes + Br- + peracetic acid | - |
Macrocystis pyrifera | ? | - |
? | |
| Tes + Br- + peracetic acid | - |
Fucus distichus | ? | - |
? | |
| Tris + Br- + peracetic acid | - |
Macrocystis pyrifera | ? | - |
? | |
| Tris + Br- + peracetic acid | - |
Fucus distichus | ? | - |
? | |
Subunits
| Subunits | Comment | Organism |
|---|---|---|
| ? | x * 74000, SDS-PAGE | Macrocystis pyrifera |
| ? | x * 65000, SDS-PAGE | Fucus distichus |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| V-BrPO | - |
Macrocystis pyrifera |
| V-BrPO | - |
Fucus distichus |
pH Optimum
| pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|
| 6 | 7 | dioxygen formation | Macrocystis pyrifera |
| 6.5 | 7 | dioxygen formation | Fucus distichus |
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