1.1.99.29: pyranose dehydrogenase (acceptor)
This is an abbreviated version!
For detailed information about pyranose dehydrogenase (acceptor), go to the full flat file.
Word Map on EC 1.1.99.29
-
1.1.99.29
-
agaricus
-
meleagris
-
basidiomycete
-
cellobiose
-
flavin-dependent
-
synthesis
-
bisporus
-
biofuel production
-
lignocellulose
-
analysis
-
pqq-dependent
-
benzoquinone
-
coprinopsis
-
glucose-methanol-choline
-
2-oxidase
-
osmium
-
pqq
-
litter-decomposing
-
quinohemoprotein
-
ferricenium
-
bioanode
-
1.1.3.10
-
biotechnology
-
carbohydrate-active
-
corynascus
-
bioelectrochemical
-
1,4-benzoquinone
-
molecular biology
-
wood-rotting
-
bioelectrocatalysis
-
degradation
- 1.1.99.29
- agaricus
- meleagris
-
basidiomycete
- cellobiose
-
flavin-dependent
- synthesis
- bisporus
- biofuel production
- lignocellulose
- analysis
-
pqq-dependent
- benzoquinone
-
coprinopsis
-
glucose-methanol-choline
-
2-oxidase
-
osmium
- pqq
-
litter-decomposing
-
quinohemoprotein
- ferricenium
-
bioanode
-
1.1.3.10
- biotechnology
-
carbohydrate-active
- corynascus
-
bioelectrochemical
- 1,4-benzoquinone
- molecular biology
-
wood-rotting
-
bioelectrocatalysis
- degradation
Reaction
Synonyms
AbPDH1, dehydrogenase, pyranose 2/3-, PDH, PDH AM, PDH AX, PDH1, PDH2, PDH3, pyranose 2-dehydrogenase, pyranose 2/3-dehydrogenase, pyranose 3-dehydrogenase, pyranose dehydrogenase, pyranose dehydrogenase 1, pyranose dehydrogenase 2, pyranose dehydrogenase 3, pyranose-quinone oxidoreductase, pyranose/acceptor oxidoreductase, pyranose:acceptor oxidoreductase, pyranose:quinone acceptor 2-oxidoreductase, quinone-dependent pyranose dehydrogenase
ECTree
1.1.99.29 pyranose dehydrogenase (acceptor)Advanced search results
results (
results (Substrates Products
Substrates Products on EC 1.1.99.29 - pyranose dehydrogenase (acceptor)
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SUBSTRATE 
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
2-dehydrolactose + acceptor
2,3-didehydrolactose + reduced acceptor
Q3L1D2
-
-
-
?
2-deoxy-D-glucose + 1,4-benzoquinone
?
-
49% of the activity with D-glucose
-
-
?
2-deoxy-D-glucose + ferricenium ion
?
-
21% of the activity with D-glucose
-
-
?
2-hydroxymethylphenyl-beta-D-glucopyranoside + acceptor
?
salicin, relative activity towards D-glucose (100%): 78%
-
-
?
3-dehydro-D-glucose + 1,4-benzoquinone
2,3-didehydro-D-glucose + hydroquinone
-
-
-
-
?
3-fluoro-3-deoxy-D-glucose + acceptor
? + reduced acceptor
-
-
-
?
4-hydroxyphenyl-beta-D-glucopyranoside + acceptor
?
arbutin
-
-
?
6-deoxy-D-glucose + acceptor
?
relative activity towards D-glucose (100%): 105%
-
-
?
a pyranoside + acceptor
3,4-didehydropyranoside + reduced acceptor
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor
aldopyranose + 1,4-benzoquinone
2-aldoketose + hydroquinone
-
more active as electron acceptor than 2,6-dichlorophenolindophenol or ferricyanide, less active than 3,5-di-tert-butyl-1,2-benzoquinone, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses
-
-
?
aldopyranose + 2,6-dichlorophenolindophenol
2-aldoketose + reduced 2,6-dichlorophenolindophenol
-
65.9% of the activity with 1,4-benzoquinone as electron acceptor, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses
-
-
?
aldopyranose + 3,5-di-tert-butyl-1,2-benzoquinone
2-aldoketose + reduced 3,5-di-tert-butyl-1,2-benzoquinone
aldopyranose + ferricyanide
2-aldoketose + ferrocyanide
-
10.4% of the activity with 1,4-benzoquinone as electron acceptor, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses
-
-
?
aldopyranose + quinone
2-aldoketose + hydroquinone
-
C-2 specific sugar oxidoreductase, highly nonspecific, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses
-
-
?
alpha,alpha-trehalose + 1,4-benzoquinone
3,3'-didehydro-alpha,alpha-trehalose + hydroquinone
alpha,alpha-trehalose + acceptor
3,3'-didehydro-alpha,alpha-trehalose + reduced acceptor
relative activity towards D-glucose (100%): 27%
-
-
?
cellobiitol + acceptor
?
relative activity towards D-glucose (100%): 77%
-
-
?
cellobiose + 2,6-dichlorophenolindophenol
2-dehydro-cellobiose + reduced 2,6-dichlorophenolindophenol
-
-
-
-
?
cellobiose + acceptor
?
relative activity towards D-glucose (100%): 70%
-
-
?
cellobiose + ferricenium ion
?
-
7% of the activity with D-glucose
-
-
?
cellotetraose + acceptor
?
relative activity towards D-glucose (100%): 14%
-
-
?
cellotriose + 1,4-benzoquinone
?
-
56% of the activity with D-glucose
-
-
?
D-allose + 1,4-benzoquinone
2-dehydro-D-allose + hydroquinone
-
30% of the activity with D-glucose
-
-
?
D-allose + acceptor
?
relative activity towards D-glucose (100%): 15%
-
-
?
D-allose + ferricenium ion
? + ferrocene
-
-
-
?
D-arabino-2-hexosulose + 1,4-benzoquinone
?
-
59% of the activity with D-glucose
-
-
?
D-arabinose + 1,4-benzoquinone
2-dehydro-D-arabinose + hydroquinone
-
18% of the activity with D-glucose
-
-
?
D-galactose + 1,4-benzoquinone
?
-
66% of the activity with D-glucose
-
-
?
D-galactose + acceptor
2-dehydro-D-galactose + reduced acceptor
relative activity towards D-glucase (100%): 99%
-
-
?
D-galactose + benzoquinone
2,3-didehydro-D-galactose + hydroquinone
Q3L1D2
-
two main reaction products
-
?
D-galactose + ferricenium ion
?
-
60% of the activity with D-glucose
-
-
?
D-glucono-1,5-lactone + acceptor
?
relative activity towards D-glucose (100%): 42%
-
-
?
D-glucono-1,5-lactone + ferricenium ion
?
-
8% of the activity with D-glucose
-
-
?
D-glucose + 2 1,4-benzoquinone
2,3-didehydro-D-glucose + 2 hydroquinone
-
-
-
-
?
D-glucose + 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)
2-dehydro-D-glucose + reduced 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)
D-glucose + 2,2'-azino-bis[3-ethylbenzothiazoline]-6-sulfonic acid
2-dehydro-D-glucose + ?
-
-
-
?
D-glucose + 2,2'-azino-bis[3-ethylbenzothiazoline]-6-sulfonic acid
3-dehydro-D-glucose + ?
-
-
-
?
D-glucose + 2,6-dichlorophenolindophenol
2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol
D-glucose + 2-(hydroxymethyl)-6-methoxy-1,4-benzoquinone
?
Q3L1D2
-
-
-
?
D-glucose + 3-ethylbenzthiazolin-6-sulfonic acid cation radical
?
Q3L1D2
-
-
-
?
D-glucose + acceptor
2,3-didehydro-D-glucose + reduced acceptor
-
dioxidation at C2 and C3
-
-
?
D-glucose + acceptor
?
relative activity towards D-glucose (100%): 100%
-
-
?
D-gulose + acceptor
?
relative activity towards D-glucose (100%): 7%
-
-
?
D-lyxose + 1,4-benzoquinone
?
-
5% of the activity with D-glucose
-
-
?
D-lyxose + ferricenium ion
?
-
5% of the activity with D-glucose
-
-
?
D-mannose + 1,4-benzoquinone
?
-
32% of the activity with D-glucose
-
-
?
D-mannose + acceptor
2-dehydro-D-mannose + reduced acceptor
-
-
-
?
D-mannose + ferricenium ion
?
-
26% of the activity with D-glucose
-
-
?
D-ribose + 1,4-benzoquinone
2-dehydro-D-ribose + hydroquinone
-
34% of the activity with D-glucose
-
-
?
D-ribose + acceptor
?
relative activity towards D-glucose (100%): 19%
-
-
?
D-ribulose + acceptor
?
relative activity towards D-glucose (100%): 17%
-
-
?
D-tagatose + acceptor
?
relative activity towards D-glucoase (100%): 67%
-
-
?
D-talose + acceptor
?
relative activity towards D-glucose (100%): 10%
-
-
?
D-xylose + 1,4-benzoquinone
?
-
72% of the activity with D-glucose
-
-
?
D-xylose + 2 1,4-benzoquinone
2,3-didehydro-D-xylose + 2 hydroquinone
-
-
-
?
D-xylose + ferricenium ion
?
-
81% of the activity with D-glucose
-
-
?
L-arabinose + 1,4-benzoquinone
2-dehydro-L-arabinose + hydroquinone
-
113% of the activity with D-glucose
-
-
?
L-arabinose + 1,4-benzoquinone
?
-
54% of the activity with D-glucose
-
-
?
L-arabinose + ferricenium ion
?
-
72% of the activity with D-glucose
-
-
?
L-glucose + 1,4-benzoquinone
2-dehydro-L-glucose + hydroquinone
-
61% of the activity with D-glucose
-
-
?
L-glucose + acceptor
?
relative activity towards D-glucose (100%): 42%
-
-
?
L-glucose + ferricenium ion
?
-
11% of the activity with D-glucose
-
-
?
L-sorbose + 1,4-benzoquinone
2-dehydro-L-sorbose + hydroquinone
-
10% of the activity with D-glucose
-
-
?
L-sorbose + acceptor
?
relative activity towards D-glucose (100%): 5%
-
-
?
lactose + acceptor
?
relative activity towards D-glucose (100%): 15%
-
-
?
lactose + acceptor
lactobiono-1,5-lactone + 2-dehydrolactose + 2,3-didehydrolactose + reduced acceptor
lactose + acceptor
lactobiono-1,5-lactone + reduced acceptor
Q3L1D2
-
-
-
?
maltose + ferricenium ion
?
-
45% of the activity with D-glucose
-
-
?
maltose + ferricenium ion
? + ferrocene
-
-
-
?
maltotetraose + acceptor
?
relative activity towards D-glucose (100%): 9%
-
-
?
maltotriose + acceptor
?
relative activity towards D-glucose (100%): 12%
-
-
?
melezitose + acceptor
?
relative activity towards D-glucose (100%): 13%
-
-
?
melibiose + acceptor
?
relative activity towards D-glucose (100%): 48%
-
-
?
methyl alpha-D-glucopyranoside + acceptor
?
relative activity towards D-glucose (100%): 107%
-
-
?
methyl alpha-D-mannopyranoside + acceptor
?
relative activity towards D-glucose (100%): 5%
-
-
?
methyl beta-D-glucopyranoside + acceptor
?
relative activity towards D-glucose (100%): 58%
-
-
?
methyl-alpha-D-galactopyranose + acceptor
?
relative activity towards D-glucose (100%): 17%
-
-
?
methyl-alpha-D-galactopyranoside + 1,4-benzoquinone
?
-
11% of the activity with D-glucose
-
-
?
methyl-alpha-D-galactopyranoside + 1,4-benzoquinone
methyl-alpha-3-dehydro-D-galactopyranoside + hydroquinone
methyl-alpha-D-galactopyranoside + ferricenium ion
?
-
8% of the activity with D-glucose
-
-
?
methyl-alpha-D-glucopyranoside + 1,4-benzoquinone
?
-
141% of the activity with D-glucose
-
-
?
methyl-alpha-D-glucopyranoside + 1,4-benzoquinone
methyl-alpha-3-dehydro-D-glucopyranoside + hydroquinone
methyl-alpha-D-glucopyranoside + ferricenium ion
?
-
143% of the activity with D-glucose
-
-
?
methyl-alpha-D-glucopyranoside + ferricenium ion
? + ferrocene
-
-
-
?
methyl-beta-D-glucopyranoside + 1,4-benzoquinone
?
-
30% of the activity with D-glucose
-
-
?
methyl-beta-D-glucopyranoside + 1,4-benzoquinone
methyl-beta-3-dehydro-D-glucopyranoside + hydroquinone
methyl-beta-D-glucopyranoside + ferricenium ion
?
-
17% of the activity with D-glucose
-
-
?
palatinose + acceptor
?
relative activity towards D-glucose (100%): 89%
-
-
?
pyranose + acceptor
2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor
sucrose + 1,4-benzoquinone
3'-dehydrosucrose + hydroquinone
-
quinone-dependent PDH oxidizes sucrose exclusively at C-3 of its terminal glucopyranosyl moiety, 11% of the activity with D-glucose
oxidation of sucrose at C-3 of its terminal glucopyranosyl moiety
-
?
sucrose + acceptor
3'-dehydrosucrose + reduced acceptor
relative activity towards D-glucose (100%): 46%
-
-
?
trehalose + ferricenium ion
?
-
8% of the activity with D-glucose
-
-
?
2,3-didehydro-D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
Q3L1D2
-
-
-
?
2,3-didehydro-D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
-
-
-
?
2,3-didehydro-D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
-
-
?
2-dehydro-D-xylose + 1,4-benzoquinone
2,3-didehydro-D-xylose + hydroquinone
Q3L1D2
-
-
-
?
2-dehydro-D-xylose + 1,4-benzoquinone
2,3-didehydro-D-xylose + hydroquinone
-
-
-
-
?
2-dehydro-D-xylose + 1,4-benzoquinone
2,3-didehydro-D-xylose + hydroquinone
-
-
-
?
2-deoxy-D-galactose + acceptor
?
relative activity towards D-glucose (100%): 31%
-
-
?
2-deoxy-D-glucose + acceptor
?
relative activity towards D-glucose (100%): 27%
-
-
?
a pyranoside + acceptor
a 3,4-didehydropyranoside + reduced acceptor
Q3L1D2
-
-
-
?
a pyranoside + acceptor
a 3,4-didehydropyranoside + reduced acceptor
-
-
-
-
?
a pyranoside + acceptor
a 3,4-didehydropyranoside + reduced acceptor
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor
-
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor
-
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor
-
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside (or 3,4-didehydropyranoside) + reduced acceptor
-
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside + reduced acceptor
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside + reduced acceptor
Q3L1D2
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside + reduced acceptor
-
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside + reduced acceptor
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside + reduced acceptor
-
-
-
?
a pyranoside + acceptor
a 3-dehydropyranoside + reduced acceptor
-
3-dehydropyranoside or 3,4-didehydropyranoside
-
?
aldopyranose + 3,5-di-tert-butyl-1,2-benzoquinone
2-aldoketose + reduced 3,5-di-tert-butyl-1,2-benzoquinone
-
4.3fold higher activity than with 1,4-benzoquinone as electron acceptor, several oligosaccharides and glycopyranosides are converted to the corresponding 2-aldoketoses/aldosuloses
-
-
?
aldopyranose + 3,5-di-tert-butyl-1,2-benzoquinone
2-aldoketose + reduced 3,5-di-tert-butyl-1,2-benzoquinone
Q3L1D2
-
-
-
?
alpha,alpha-trehalose + 1,4-benzoquinone
3,3'-didehydro-alpha,alpha-trehalose + hydroquinone
-
quinone-dependent PDH oxidizes alpha,alpha-trehalose at C-3 and C-3, 5% of the activity with D-glucose
with 3-dehydro-alpha,alpha-trehalose as reaction intermediate
-
?
alpha,alpha-trehalose + 1,4-benzoquinone
3,3'-didehydro-alpha,alpha-trehalose + hydroquinone
-
quinone-dependent PDH oxidizes alpha,alpha-trehalose at C-3 and C-3, 5% of the activity with D-glucose
with 3-dehydro-alpha,alpha-trehalose as reaction intermediate
-
?
cellobiose + 1,4-benzoquinone
?
-
13% of the activity with D-glucose
-
-
?
cellobiose + ferrocenium ion
2-dehydro-cellobiose + ferrocene
-
-
-
?
cellobiose + ferrocenium ion
2-dehydro-cellobiose + ferrocene
-
-
-
?
cellobiose + ferrocenium ion
2-dehydro-cellobiose + ferrocene
-
-
-
?
D-galactose + 1,4-benzoquinone
2-dehydro-D-galactose + hydroquinone
-
88% of the activity with D-glucose
-
-
?
D-galactose + 1,4-benzoquinone
2-dehydro-D-galactose + hydroquinone
-
PDH oxidizes D-galactose exclusively at C-2 to produce D-lyxo-hexos-2-ulose
2-keto-D-galactose
-
?
D-galactose + 1,4-benzoquinone
2-dehydro-D-galactose + hydroquinone
-
quinone-dependent PDH oxidizes D-galactose exclusively at C-2
-
-
?
D-galactose + 1,4-benzoquinone
2-dehydro-D-galactose + hydroquinone
-
quinone-dependent PDH oxidizes D-galactose exclusively at C-2
-
-
?
D-galactose + 1,4-benzoquinone
2-dehydro-D-galactose + hydroquinone
-
PDH oxidizes D-galactose exclusively at C-2 to produce D-lyxo-hexos-2-ulose
2-keto-D-galactose
-
?
D-galactose + benzoquinone
2-dehydro-D-galactose + hydroquinone
Q3L1D2
-
two main reaction products
-
?
D-galactose + benzoquinone
2-dehydro-D-galactose + hydroquinone
-
-
no 2,3-didehydro-d-galactose is detectable
-
?
D-galactose + ferricenium ion
? + ferrocene
-
-
-
?
D-galactose + ferrocenium ion
2-dehydro-D-galactose + ferrocene
-
-
-
?
D-galactose + ferrocenium ion
2-dehydro-D-galactose + ferrocene
-
-
-
?
D-galactose + ferrocenium ion
2-dehydro-D-galactose + ferrocene
-
-
-
?
D-galactose + ferrocenium ion
2-dehydro-D-galactose + ferrocene
-
-
-
?
D-galactose + ferrocenium ion
2-dehydro-D-galactose + ferrocene
-
-
-
?
D-galactose + ferrocenium ion
2-dehydro-D-galactose + ferrocene
-
-
-
-
?
D-galactose + ferrocenium ion
2-dehydro-D-galactose + ferrocene
-
-
-
?
D-glucono-1,5-lactone + 1,4-benzoquinone
?
-
118% of the activity with D-glucose
-
-
?
D-glucono-1,5-lactone + 1,4-benzoquinone
?
-
20% of the activity with D-glucose
-
-
?
D-glucose + 1,4-benzoquinone
2,3-didehydro-D-glucose + hydroquinone
Q3L1D2
-
-
-
?
D-glucose + 1,4-benzoquinone
2,3-didehydro-D-glucose + hydroquinone
-
-
-
-
?
D-glucose + 1,4-benzoquinone
2,3-didehydro-D-glucose + hydroquinone
-
-
-
?
D-glucose + 1,4-benzoquinone
2-dehydro-D-glucose + ?
-
-
-
?
D-glucose + 1,4-benzoquinone
2-dehydro-D-glucose + hydroquinone
-
-
-
?
D-glucose + 1,4-benzoquinone
2-dehydro-D-glucose + hydroquinone
-
-
D-arabino-2-hexosulose, 2-ketoglucose
-
?
D-glucose + 1,4-benzoquinone
2-dehydro-D-glucose + hydroquinone
-
-
-
?
D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
PDH catalyzes the C-2 and C-3 oxidation of D-glucose, quinone-dependent
or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose, products are 2-keto-D-glucose and, preferentially, 3-keto-D-glucose, both are subsequently oxidized by PDH to 2,3-diketo-D-glucose
-
?
D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
quinone-dependent PDH catalyzes C-2 or, preferentially, C-3 dehydrogenation of D-glucose
or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose
-
?
D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
quinone-dependent PDH catalyzes C-2 or, preferentially, C-3 dehydrogenation of D-glucose
or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose
-
?
D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
PDH catalyzes the C-2 and C-3 oxidation of D-glucose, quinone-dependent
or 2-dehydro-D-glucose or 2,3-didehydro-D-glucose, products are 2-keto-D-glucose and, preferentially, 3-keto-D-glucose, both are subsequently oxidized by PDH to 2,3-diketo-D-glucose
-
?
D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
oxidizes D-glucose exclusively at C-3, D-glucose is the preferred electron donor susbtrate
-
-
?
D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
simultaneous C-2 and C-3 oxidation of free D-glucose
or 2-dehydro-D-glucose
-
?
D-glucose + 1,4-benzoquinone
3-dehydro-D-glucose + hydroquinone
-
simultaneous C-2 and C-3 oxidation of free D-glucose
or 2-dehydro-D-glucose
-
?
D-glucose + 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)
2-dehydro-D-glucose + reduced 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)
-
-
-
?
D-glucose + 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)
2-dehydro-D-glucose + reduced 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid)
-
-
-
?
D-glucose + 2,6-dichlorophenolindophenol
2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol
-
-
-
?
D-glucose + 2,6-dichlorophenolindophenol
2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol
-
-
-
?
D-glucose + 2,6-dichlorophenolindophenol
2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol
-
-
-
?
D-glucose + 2,6-dichlorophenolindophenol
2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol
-
-
-
?
D-glucose + 2,6-dichlorophenolindophenol
2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol
-
-
-
-
?
D-glucose + 2,6-dichlorophenolindophenol
2-dehydro-D-glucose + reduced 2,6-dichlorophenolindophenol
-
-
-
?
D-glucose + acceptor
2-dehydro-D-glucose + reduced acceptor
-
-
-
?
D-glucose + acceptor
2-dehydro-D-glucose + reduced acceptor
the enzyme oxidizes D-glucose at both the C2 and C3 position but the C2 position is the primary site of attack
-
-
?
D-glucose + acceptor
3-dehydro-D-glucose + reduced acceptor
Q3L1D2
-
-
-
?
D-glucose + acceptor
3-dehydro-D-glucose + reduced acceptor
-
-
-
-
?
D-glucose + benzoquinone
2,3-didehydro-D-glucose + hydroquinone
Q3L1D2
3-oxo-D-glucose, 1-alpha-3-dehydro-d-glucopyranose, 1-beta-3-dehydro-d-glucopyranose, 1-alpha-3-dehydro-d-glucopyranose hydrate, 1-beta-3-dehydro-d-glucopyranose hydrate, 2-dehydro-d-glucose, 1-alpha-2,3-bis-dehydro-d-glucopyranose bis-hydrate as minor reaction products
-
-
?
D-glucose + benzoquinone
2,3-didehydro-D-glucose + hydroquinone
-
pH 3
-
-
?
D-glucose + ferricenium ion
2-dehydro-D-glucose + ferrocene
-
-
-
?
D-glucose + ferricenium ion
2-dehydro-D-glucose + ferrocene
-
-
-
?
D-glucose + ferricenium ion
3-dehydro-D-glucose + ferrocene
Q3L1D2
-
-
-
?
D-glucose + ferricenium ion
3-dehydro-D-glucose + ferrocene
-
oxidizes D-glucose exclusively at C-3, D-glucose is the preferred electron donor susbtrate
-
-
?
D-glucose + ferricenium ion
3-dehydro-D-glucose + ferrocene
-
-
-
?
D-glucose + ferricenium ion
3-dehydro-D-glucose + ferrocene
-
-
-
?
D-glucose + ferrocenium ion
2-dehydro-D-glucose + ferrocene
ferrocenium ion is the preferred electron acceptor
-
-
?
D-glucose + ferrocenium ion
2-dehydro-D-glucose + ferrocene
-
-
-
?
D-glucose + ferrocenium ion
2-dehydro-D-glucose + ferrocene
-
-
-
?
D-glucose + ferrocenium ion
2-dehydro-D-glucose + ferrocene
-
-
-
-
?
D-glucose + ferrocenium ion
2-dehydro-D-glucose + ferrocene
-
-
-
?
D-glucose + ferrocenium ion
2-dehydro-D-glucose + ferrocene
-
-
-
-
?
D-glucose + ferrocenium ion
3-dehydro-D-glucose + ferrocene
-
-
-
-
?
D-glucose + ferrocenium ion
3-dehydro-D-glucose + ferrocene
-
-
-
?
D-maltose + acceptor
?
relative activity towards D-glucose (100%): 61%
-
-
?
D-mannose + acceptor
?
relative activity towards D-glucose (100%): 24%
-
-
?
D-mannose + ferricenium ion
? + ferrocene
-
-
-
?
D-mannose + ferrocenium ion
2-dehydro-D-mannose + ferrocene
-
-
-
?
D-xylose + 1,4-benzoquinone
2-dehydro-D-xylose + hydroquinone
-
116% of the activity with D-glucose
-
-
?
D-xylose + 1,4-benzoquinone
2-dehydro-D-xylose + hydroquinone
-
quinone-dependent PDH oxidizes D-xylose at C-2 to 2-keto-D-xylose and successively at C-3 to 2,3-diketo-D-xylose
or 2,3-didehydro-D-xylose
-
?
D-xylose + 1,4-benzoquinone
2-dehydro-D-xylose + hydroquinone
-
quinone-dependent PDH oxidizes D-xylose at C-2 to 2-keto-D-xylose and successively at C-3 to 2,3-diketo-D-xylose
or 2,3-didehydro-D-xylose
-
?
D-xylose + 1,4-benzoquinone
2-dehydro-D-xylose + hydroquinone
Q3L1D2
-
-
-
?
D-xylose + 1,4-benzoquinone
2-dehydro-D-xylose + hydroquinone
-
-
-
-
?
D-xylose + 1,4-benzoquinone
2-dehydro-D-xylose + hydroquinone
-
-
-
?
D-xylose + acceptor
?
relative activity towards D-glucose (100%): 113%
-
-
?
D-xylose + ferricenium ion
? + ferrocene
-
-
-
?
D-xylose + ferrocenium ion
2-dehydro-D-xylose + ferrocene
-
-
-
?
erlose + 1,4-benzoquinone
3-dehydroerlose + hydroquinone
-
quinone-dependent PDH oxidizes erlose at exclusively C-3 of its terminal glucopyranosyl moiety, 9% of the activity with D-glucose
-
-
?
erlose + 1,4-benzoquinone
3-dehydroerlose + hydroquinone
-
quinone-dependent PDH oxidizes erlose at exclusively C-3 of its terminal glucopyranosyl moiety, 9% of the activity with D-glucose
-
-
?
L-arabinose + acceptor
?
relative activity towards D-glucose (100%): 100%
-
-
?
L-arabinose + ferrocenium ion
2-dehydro-L-arabinose + ferrocene
-
-
-
?
L-arabinose + ferrocenium ion
2-dehydro-L-arabinose + ferrocene
-
-
-
?
L-arabinose + ferrocenium ion
2-dehydro-L-arabinose + ferrocene
-
-
-
?
L-fucose + acceptor
?
relative activity towards D-glucose (100%): 7%
-
-
?
lactose + acceptor
lactobiono-1,5-lactone + 2-dehydrolactose + 2,3-didehydrolactose + reduced acceptor
Q3L1D2
-
-
-
?
lactose + acceptor
lactobiono-1,5-lactone + 2-dehydrolactose + 2,3-didehydrolactose + reduced acceptor
-
-
-
-
?
lactose + acceptor
lactobiono-1,5-lactone + 2-dehydrolactose + 2,3-didehydrolactose + reduced acceptor
-
-
-
?
lactose + ferricenium ion
? + ferrocene
-
-
-
?
lactose + ferrocenium ion
? + ferrocene
48% of the lactose is converted and yields 88% lactobionic acid and 12% 2-dehydrolactose
-
-
?
lactose + ferrocenium ion
? + ferrocene
the enzyme converts lactose to nearly 100%, producing 69% lactobionic acid and 31% 2-dehydrolactose
-
-
?
maltose + 1,4-benzoquinone
?
-
64% of the activity with D-glucose
-
-
?
maltotriose + 1,4-benzoquinone
?
-
70% of the activity with D-glucose
-
-
?
maltotriose + 1,4-benzoquinone
?
-
21% of the activity with D-glucose
-
-
?
maltotriose + ferricenium ion
?
-
14% of the activity with D-glucose
-
-
?
maltotriose + ferricenium ion
? + ferrocene
-
-
-
?
melizitose + 1,4-benzoquinone
3-dehydromelizitose + hydroquinone
-
quinone-dependent PDH oxidizes melezitose exclusively at C-3 of its terminal glucopyranosyl moiety, 7% of the activity with D-glucose
-
-
?
melizitose + 1,4-benzoquinone
3-dehydromelizitose + hydroquinone
-
quinone-dependent PDH oxidizes melezitose exclusively at C-3 of its terminal glucopyranosyl moiety, 7% of the activity with D-glucose
-
-
?
methyl-alpha-D-galactopyranoside + 1,4-benzoquinone
methyl-alpha-3-dehydro-D-galactopyranoside + hydroquinone
-
23% of the activity with D-glucose
-
-
?
methyl-alpha-D-galactopyranoside + 1,4-benzoquinone
methyl-alpha-3-dehydro-D-galactopyranoside + hydroquinone
-
formation of the C-3 carbonyl derivative, 7% of the activity with D-glucose
-
-
?
methyl-alpha-D-glucopyranoside + 1,4-benzoquinone
methyl-alpha-3-dehydro-D-glucopyranoside + hydroquinone
-
117% of the activity with D-glucose
-
-
?
methyl-alpha-D-glucopyranoside + 1,4-benzoquinone
methyl-alpha-3-dehydro-D-glucopyranoside + hydroquinone
-
formation of the C-3 carbonyl derivative, 126% of the activity with D-glucose
-
-
?
methyl-beta-D-glucopyranoside + 1,4-benzoquinone
methyl-beta-3-dehydro-D-glucopyranoside + hydroquinone
-
69% of the activity with D-glucose
-
-
?
methyl-beta-D-glucopyranoside + 1,4-benzoquinone
methyl-beta-3-dehydro-D-glucopyranoside + hydroquinone
-
formation of the C-3 carbonyl derivative, 20% of the activity with D-glucose
-
-
?
pyranose + acceptor
2,3-didehydropyranose + reduced acceptor
-
-
-
?
pyranose + acceptor
2,3-didehydropyranose + reduced acceptor
Q3L1D2
-
-
-
?
pyranose + acceptor
2,3-didehydropyranose + reduced acceptor
-
-
-
-
?
pyranose + acceptor
2,3-didehydropyranose + reduced acceptor
-
-
-
?
pyranose + acceptor
2,3-didehydropyranose + reduced acceptor
-
-
-
?
pyranose + acceptor
2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor
-
-
-
-
?
pyranose + acceptor
2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor
-
-
-
-
?
pyranose + acceptor
2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor
-
-
-
-
?
pyranose + acceptor
2-dehydropyranose (or 3-dehydropyranose or 2,3-didehydropyranose) + reduced acceptor
-
-
-
-
?
pyranose + acceptor
2-dehydropyranose + reduced acceptor
Q3L1D2
-
-
-
?
pyranose + acceptor
2-dehydropyranose + reduced acceptor
-
-
-
-
?
pyranose + acceptor
2-dehydropyranose + reduced acceptor
-
-
-
?
pyranose + acceptor
2-dehydropyranose + reduced acceptor
-
-
-
?
pyranose + acceptor
2-dehydropyranose + reduced acceptor
-
2-dehydropyranose or 1-dehydropyranose or 3-dehydropyranose or 2,3-didehydropyranose
-
?
pyranose + acceptor
3-dehydropyranose + reduced acceptor
Q3L1D2
-
-
-
?
pyranose + acceptor
3-dehydropyranose + reduced acceptor
-
-
-
-
?
pyranose + acceptor
3-dehydropyranose + reduced acceptor
-
-
-
?
pyranose + acceptor
3-dehydropyranose + reduced acceptor
-
-
-
?
pyranoside + acceptor
3,4-didehydropyranoside + reduced acceptor
Q3L1D2
-
-
-
?
pyranoside + acceptor
3,4-didehydropyranoside + reduced acceptor
-
-
-
?
sucrose + 1,4-benzoquinone
?
-
9% of the activity with D-glucose
-
-
?
trehalose + 1,4-benzoquinone
?
-
7% of the activity with D-glucose
-
-
?
xylooligosaccharide + acceptor
?
activity of the PDH1 enzyme from Agaricus bisporus toward the tested xylooligosaccharides is higher than that measured for the PDH1 enzyme from Leucoagaricus meleagris. Activity values decrease with increasing length of the xylooligosaccharide and when using acidic rather than neutral substrates. The enzyme from Agaricus bisporus (AbPDH1) fully oxidizes all linear xylooligosaccharides, and 60-100% of all substituted xylooligosaccharides, after 24 h under the tested reaction conditions. Oxidation is restricted to the reducing and non-reducing xylopyranosyl residues
-
-
?
additional information
?
-
-
oxidative carbohydrate metabolism, pyranose 2-dehydrogenase may play an important role in fungal lignocellulose decomposition by interconnecting ligninolysis with degradation of cell wall polysaccharide components
-
-
?
additional information
?
-
-
enzyme is incapable of reducing O2 to H2O2, not: cytochrome c, NAD(P)+, nitroblue tetrazolium, low or no activity with D-altrose, D-fructose, D-lyxose, D-mannose, D-arabinitol, D-glucitol, D-mannitol or erythritol
-
-
?
additional information
?
-
-
with 1,4-benzoquinone as electron acceptor, PDH catalyzes the oxidation of numerous monosaccharides and oligosaccharides
-
-
?
additional information
?
-
-
with 1,4-benzoquinone as electron acceptor, PDH catalyzes the oxidation of numerous monosaccharides and oligosaccharides
-
-
?
additional information
?
-
-
broad selectivity for sugar substrates, O2 does not act as oxidant, not: D-allose, D-altrose, D-arabinose, D-ribose, D-fructose, L-sorbose, lactose, D-arabinitol, dulcitol, D-mannitol
-
-
?
additional information
?
-
-
extremely broad substrate tolerance
-
-
?
additional information
?
-
-
PDH can oxidise its substrate at the C-1, C-2 or C-3 as well as perform double oxidation at C-1,2, C-2,3 and it has no anomeric specificity. PDH does not show any detectable activity with oxygen
-
-
?
additional information
?
-
O2 is a poor electron acceptor
-
-
?
additional information
?
-
-
extremely broad substrate tolerance
-
-
?
