1.13.11.41: 2,4'-dihydroxyacetophenone dioxygenase
This is an abbreviated version!
For detailed information about 2,4'-dihydroxyacetophenone dioxygenase, go to the full flat file.
Word Map on EC 1.13.11.41
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1.13.11.41
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cupin
-
alcaligenes
-
homotetramer
-
formic
-
4-hydroxybenzoic
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ketone
-
chymotrypsinolysis
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tridentate
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biomimetic
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nonhaem
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non-heme
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2-hydroxyacetophenone
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equiv
- 1.13.11.41
-
cupin
- alcaligenes
-
homotetramer
-
formic
-
4-hydroxybenzoic
- ketone
-
chymotrypsinolysis
-
tridentate
-
biomimetic
-
nonhaem
-
non-heme
- 2-hydroxyacetophenone
-
equiv
Reaction
Synonyms
(4-hydroxybenzoyl)methanol oxygenase, DAD, DHAP dioxygenase
ECTree
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Reaction
Reaction on EC 1.13.11.41 - 2,4'-dihydroxyacetophenone dioxygenase
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2,4'-dihydroxyacetophenone + O2 = 4-hydroxybenzoate + formate
the cleavage mechanism of the aliphatic C-C bond catalyzed by 2,4'-dihydroxyacetophenone dioxygenase, quantum mechanics/molecular mechanics calculations. The reactant complex may firstly undergo a triplet-quintet crossing to initiate the reaction and then the subsequent chemistry mainly occurs on the quintet state surface, modeling of the enzyme-substrate complex, overview