1.13.11.53: acireductone dioxygenase (Ni2+-requiring)

This is an abbreviated version!
For detailed information about acireductone dioxygenase (Ni2+-requiring), go to the full flat file.

Word Map on EC 1.13.11.53

Reaction

1,2-dihydroxy-5-(methylsulfanyl)pent-1-en-3-one
+
O2
=
3-(methylsulfanyl)propanoate
+
formate
+
CO

Synonyms

2-hydroxy-3-keto-5-thiomethylpent-1-ene dioxygenase, aci-reductone dioxygenase, acidoreductone dioxygenase, acireductone dioxygenase, ADI1, ARD, ARD1, human aci-reductone dioxygenase 1, membrane-type 1 matrix metalloproteinase cytoplasmic tail binding protein-1, MtnD, Ni(II)-ARD

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.53 acireductone dioxygenase (Ni2+-requiring)

Substrates Products

Substrates Products on EC 1.13.11.53 - acireductone dioxygenase (Ni2+-requiring)

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(1Z)-1,2-dihydroxyhex-1-en-3-one + O2
n-butanoic acid + formic acid + CO
show the reaction diagram
1,2-dihydroxy-3-keto-1-hexene + O2
?
show the reaction diagram
-
incorporation of O2 into C1 and C3 of 1,2-dihydroxy-3-keto-1-hexene
-
-
?
1,2-dihydroxy-3-oxo-3-phenyl-1-propene + O2
?
show the reaction diagram
-
-
-
-
?
1,2-dihydroxy-5-(methylthio)pent-1-en-3-one + O2
3-(methylthio)-2-oxobutanoate + formate
show the reaction diagram
-
-
-
-
?
1,2-dihydroxy-5-(methylthio)pent-1-en-3-one + O2
3-(methylthio)propanoate + formate + CO
show the reaction diagram
1,2-dihydroxy-5-(methylthio)pent-1-en-3-one + O2
4-methylthio-2-ketobutyrate + formate + CO
show the reaction diagram
-
-
-
-
?
1,2-dihydroxyhex-1-en-3-one + O2
butyrate + formate + CO
show the reaction diagram
-
-
-
-
?
1-phosphonooxy-2,2-dihydroxy-3-oxo-3-phenylpropane + O2
?
show the reaction diagram
part of the Met salvage pathway
-
-
?
additional information
?
-