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1.13.11.92: fatty acid alpha-dioxygenase

This is an abbreviated version!
For detailed information about fatty acid alpha-dioxygenase, go to the full flat file.

Word Map on EC 1.13.11.92

Reaction

a fatty acid
+
O2
=
a (2R)-2-hydroperoxyfatty acid

Synonyms

alpha-dioxygenase, alpha-DOX1, AXX17_At3g00510, cce_4307, DOX1, fatty acid alpha-oxidase, PADOX-1, Piox

ECTree

     1 Oxidoreductases
         1.13 Acting on single donors with incorporation of molecular oxygen (oxygenases)
             1.13.11 With incorporation of two atoms of oxygen
                1.13.11.92 fatty acid alpha-dioxygenase

Substrates Products

Substrates Products on EC 1.13.11.92 - fatty acid alpha-dioxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
10-methyldodecanoic acid + O2
(2R)-10-methyl-2-hydroperoxy-dodecanoic acid
show the reaction diagram
-
-
-
?
11-methyldodecanoic acid + O2
(2R)-11-methyl-2-hydroperoxy-dodecanoic acid
show the reaction diagram
-
-
-
?
11-methyltridecanoic acid + O2
(2R)-11-methyl-2-hydroperoxy-tridecanoic acid
show the reaction diagram
-
-
-
?
12-methyltridecanoic acid + O2
(2R)-12-methyl-2-hydroperoxy-tridecanoic acid
show the reaction diagram
-
-
-
?
13-methylpentadecanoic acid + O2
(2R)-13-methyl-2-hydroperoxy-pentadecanoic acid
show the reaction diagram
-
-
-
?
13-methyltetradecanoic acid + O2
(2R)-13-methyl-2-hydroperoxy-tetradecanoic acid
show the reaction diagram
-
-
-
?
14-methylpentadecanoic acid + O2
(2R)-14-methyl-2-hydroperoxy-pentadecanoic acid
show the reaction diagram
-
-
-
?
3-thiamyristate + O2
(2R)-2-hydroperoxy-3-thiatetradecanoic acid
show the reaction diagram
-
-
-
?
arachidonic acid + O2
(4Z,7Z,10Z,13Z)-nonadeca-5,8,11,14-trienal + (2R)-2-hydroxy-(5Z,8Z,11Z,14Z)-eicosa-5,8,11,14-trienoic acid + (4Z,7Z,10Z,13Z)-nonadeca-4,7,10,13-tetraenoic acid + CO2
show the reaction diagram
O82031
-
-
-
?
decanoic acid + O2
(2R)-2-hydroperoxy-nonanal + CO2 + H2O
show the reaction diagram
-
-
-
-
?
dodecanoic acid + O2
(2R)-2-hydroperoxy-undecanal + CO2 + H2O
show the reaction diagram
-
-
-
-
?
gamma-linolenic acid + O2
?
show the reaction diagram
-
-
-
?
heptadecanoic acid + O2
(2R)-2-hydroperoxy-heptadecanoic acid
show the reaction diagram
-
-
-
-
?
hexadecanoic acid + O2
(2R)-2-hydroperoxy-hexadecanoic acid
show the reaction diagram
-
more than 99% enantiomeric excess
-
-
?
hexadecanoic acid + O2
(2R)-2-hydroperoxy-pentadecanal + CO2 + H2O
show the reaction diagram
-
-
-
-
?
lauric acid + O2
(R)-2-hydroperoxydodecanoic acid
show the reaction diagram
-
-
-
-
?
linoleic acid + O2
(2R)-2-hydroperoxy-(9Z,12Z)-octadeca-9,12-dienoic acid
show the reaction diagram
linoleic acid + O2
(8Z,11Z)-heptadeca-8,11-dienal + (2R)-2-hydroxy-(9Z,12Z)-octadeca-9,12-dienoic acid + (8Z,11Z)-heptadeca-8,11-dienoic acid + CO2
show the reaction diagram
linolenic acid + O2
(2R)-2-hydroperoxy-(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid
show the reaction diagram
linolenic acid + O2
(8Z,11Z,14Z)-heptadeca-8,11,14-trienal + (2R)-2-hydroxy-(9Z,12Z,15Z)-octadeca-9,12,15-trienoic acid + (8Z,11Z,14Z)-heptadeca-8,11,14-trienoic acid + CO2
show the reaction diagram
myristic acid + O2
(2R)-2-hydroperoxy-tetradecanoic acid
show the reaction diagram
oleic acid + O2
(2R)-2-hydroperoxy-(9Z)-octadeca-9-enoic acid
show the reaction diagram
oleic acid + O2
(8Z)-heptadeca-8-enal + (2R)-2-hydroxy-(9Z)-octadeca-9-enoic acid + (8Z)-heptadeca-8-enoic acid + CO2
show the reaction diagram
palmitic acid + O2
(R,S)-2-hydroperoxypalmitic acid
show the reaction diagram
palmitic acid + O2
pentadecanal + 2-hydroxyhexadecanoic acid + pentadecanoic acid + CO2
show the reaction diagram
palmitoleic acid + O2
(R,S)-2-hydroperoxypalmitic acid
show the reaction diagram
-
-
-
?
pentadecanoic acid + O2
(2R)-2-hydroperoxy-pentadecanoic acid
show the reaction diagram
-
-
-
-
?
tetradecanoic acid + O2
(2R)-2-hydroperoxy-tridecanal + CO2 + H2O
show the reaction diagram
-
-
-
-
?
additional information
?
-