1.14.11.75: 31-hydroxy-L-isoleucine 4-dioxygenase
This is an abbreviated version!
For detailed information about 31-hydroxy-L-isoleucine 4-dioxygenase, go to the full flat file.
Reaction
Synonyms
4'-hydroxy-L-isoleucine 4-dioxygenase, HilB, L-4'-hydroxyisoleucine, 2-oxoglutarate: oxygen oxidoreductase (4-hydroxylating), L-isoleucine-4'-dioxygenase
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Natural Substrates Products on EC 1.14.11.75 - 31-hydroxy-L-isoleucine 4-dioxygenase
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REACTION DIAGRAM
(3S)-3'-hydroxy-L-isoleucine + 2-oxoglutarate + O2
(3S,4R)-3',4-dihydroxy-L-isoleucine + succinate + CO2
(3S,4R)-3',4-dihydroxy-L-isoleucine + succinate + CO2
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(3S)-3'-hydroxy-L-isoleucine + 2-oxoglutarate + O2
(3S,4R)-3',4-dihydroxy-L-isoleucine + succinate + CO2
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L-isoleucine 3'-hydroxylase HilA and 3'-hydroxy-L-isoleucine 4-hydroxylase HilB catalyze the consecutive hydroxylation of L-isoleucine at the C-3' and C-4 positions, respectively, to synthesize L-3',4-dihydroxyisoleucine. When expressed without HilA, HilB acts as a minimally effective L-isoleucine-4-dioxygenase
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additional information
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L-isoleucine 3'-hydroxylase HilA and 3'-hydroxy-L-isoleucine 4-hydroxylase HilB catalyze the consecutive hydroxylation of L-isoleucine at the C-3' and C-4 positions, respectively, to synthesize L-3',4-dihydroxyisoleucine. When expressed without HilA, HilB acts as a minimally effective L-isoleucine-4-dioxygenase
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