1.14.13.216: asperlicin C monooxygenase
This is an abbreviated version!
For detailed information about asperlicin C monooxygenase, go to the full flat file.
Reaction
Synonyms
aspB
ECTree
1.14.13.216 asperlicin C monooxygenaseAdvanced search results
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Natural Substrates Products on EC 1.14.13.216 - asperlicin C monooxygenase
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NATURAL SUBSTRATE 
NATURAL PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
asperlicin C + FADH2 + O2
asperlicin E + FAD + H2O
-
the instability of the product generated from the reaction of AspB with the enantiomer of asperlicin C (ent-asperlicin C) hinders full characterization, formation of an oxidized product, which is stalled prior to intramolecular cyclization en route to an asperlicin E type product
with NAD(P)H as reducing element, product determination by NMR spectroscopy
-
?
asperlicin C + FADH2 + O2
asperlicin E + FAD + H2O
-
the instability of the product generated from the reaction of AspB with the enantiomer of asperlicin C (ent-asperlicin C) hinders full characterization, formation of an oxidized product, which is stalled prior to intramolecular cyclization en route to an asperlicin E type product
with NAD(P)H as reducing element, product determination by NMR spectroscopy
-
?
additional information
?
-
-
the enzyme converts synthetic asperlicin C or D (and their enantiomers) in the presence of proposed cosubstrate O2 to new products. No activity with asperlicin D and fumiquinazoline F by enzyme AspB
-
-
?
additional information
?
-
-
the enzyme converts synthetic asperlicin C or D (and their enantiomers) in the presence of proposed cosubstrate O2 to new products. No activity with asperlicin D and fumiquinazoline F by enzyme AspB
-
-
?
