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1.14.13.245: assimilatory dimethylsulfide S-monooxygenase

This is an abbreviated version!
For detailed information about assimilatory dimethylsulfide S-monooxygenase, go to the full flat file.

Reaction

Dimethyl sulfide
+
NADH
+
H+
+
O2
=
dimethyl sulfoxide
+
NAD+
+
H2O

Synonyms

DMS oxygenase, DsoABCDEF, dsoBCDEF

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.13 With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.13.245 assimilatory dimethylsulfide S-monooxygenase

Substrates Products

Substrates Products on EC 1.14.13.245 - assimilatory dimethylsulfide S-monooxygenase

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
1,1-dichloro-1-propene + O2 + NADH + H+
? + NAD+ + H2O
show the reaction diagram
high rate of oxidation
no detection of oxidation products, but detection of chloride ions released stoichiometrically in the process of oxidation
-
?
1,1-dichloroethylene + O2 + NADH + H+
? + NAD+ + H2O
show the reaction diagram
1,3-dichloro-1-propene + O2 + NADH + H+
? + NAD+ + H2O
show the reaction diagram
high rate of oxidation
no detection of oxidation products, but detection of chloride ions released stoichiometrically in the process of oxidation
-
?
1-butene + O2 + NADH + H+
1,2-butylene oxide + NAD+ + H2O
show the reaction diagram
-
-
-
?
2,3-dichloro-1-propene + O2 + NADH + H+
? + NAD+ + H2O
show the reaction diagram
high rate of oxidation
no detection of oxidation products, but detection of chloride ions released stoichiometrically in the process of oxidation
-
?
3,4-dichloro-1-butene + O2 + NADH + H+
3,4-dichloro-1,2-butylene oxide + NAD+ + H2O
show the reaction diagram
-
diastereomeric product
-
?
cis-1,2-dichloroethylene + O2 + NADH + H+
cis-1,2-dichlorooxirane + NAD+ + H2O
show the reaction diagram
cis-1,4-dichloro-2-butene + O2 + NADH + H+
cis-1,4-dichloro-2,3-butylene oxide + NAD+ + H2O
show the reaction diagram
-
-
-
?
cis-2,3-butene + O2 + NADH + H+
2,3-butylene oxide + NAD+ + H2O
show the reaction diagram
-
-
-
?
cis-dichloroethylene + O2 + NADH + H+
cis-dichlorooxirane + NAD+ + H2O
show the reaction diagram
-
-
-
?
dimethyl sulfide + NADH + H+ + O2
dimethyl sulfoxide + NAD+ + H2O
show the reaction diagram
dimethyl sulfoxide + NADH + H+ + O2
dimethyl sulfone + NAD+ + H2O
show the reaction diagram
O32428; O32429; O32430; O32431; O32432; O32433
-
-
-
?
isobutene + O2 + NADH + H+
isobutylene oxide + NAD+ + H2O
show the reaction diagram
-
-
-
?
propene + O2 + NADH + H+
propylene oxide + NAD+ + H2O
show the reaction diagram
-
-
-
?
trans-1,2-dichloroethylene + O2 + NADH + H+
2,3-dichlorooxirane + NAD+ + H2O
show the reaction diagram
trans-1,4-dichloro-2-butene + O2 + NADH + H+
trans-1,4-dichloro-2,3-butylene oxide + NAD+ + H2O
show the reaction diagram
-
-
-
?
trans-dichloroethylene + O2 + NADH + H+
trans-dichlorooxirane + NAD+ + H2O
show the reaction diagram
-
-
-
?
trichloroethylene + O2 + NADH + H+
? + NAD+ + H2O
show the reaction diagram
additional information
?
-