1.14.14.45: aromatic aldoxime N-monooxygenase

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For detailed information about aromatic aldoxime N-monooxygenase, go to the full flat file.

Reaction

Synonyms

At4g31500, CYP83B1, cytochrome P450 83B1, HM347235

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

                1.14.14.45 aromatic aldoxime N-monooxygenase

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2	AA Sequence
5	Cloned(Commentary)
2	Cofactor
10	General Information
3	Inhibitors
3	kcat/KM [mM/s]
7	KM Value [mM]
8	Natural Substrates/ Products (Substrates)
12	Organism
4	Pathway
1	pH Optimum
6	Reaction
12	Reference
3	Source Tissue
22	Substrates and Products (Substrate)
12	Synonyms
1	Systematic Name
9	Turnover Number [1/s]

Reaction

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Reaction on EC 1.14.14.45 - aromatic aldoxime N-monooxygenase

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REACTION

REACTION DIAGRAM

COMMENTARY

ORGANISM

UNIPROT

LITERATURE

(E)-indol-3-ylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 = S-[(E)-N-hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + [oxidized NADPH-hemoprotein reductase] + 2 H2O

(1), overall reaction

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(E)-indol-3-ylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 = 1-(1H-indol-3-yl)-2-aci-nitroethane + [oxidized NADPH-hemoprotein reductase] + H2O

(1a)

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(E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + glutathione + O2 = S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + [oxidized NADPH-hemoprotein reductase] + 2 H2O

(2), overall reaction

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(E)-phenylacetaldehyde oxime + [reduced NADPH-hemoprotein reductase] + O2 = 1-aci-nitro-2-phenylethane + [oxidized NADPH-hemoprotein reductase] + H2O

(2a)

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1-(1H-indol-3-yl)-2-aci-nitroethane + glutathione = S-[(E)-N-hydroxy(indol-3-yl)acetimidoyl]-L-glutathione + H2O

(1b), spontaneous

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1-aci-nitro-2-phenylethane + glutathione = S-[(Z)-N-hydroxy(phenyl)acetimidoyl]-L-glutathione + H2O

(2b), spontaneous

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