1.14.14.49: 12-hydroxyjasmonoyl-L-amino acid 12-hydroxylase
This is an abbreviated version!
For detailed information about 12-hydroxyjasmonoyl-L-amino acid 12-hydroxylase, go to the full flat file.
Reaction
+ 2 [reduced NADPH-hemoprotein reductase] + 2 O2 = + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O
Synonyms
CYP94C1, CYP94C3, jasmonoyl-L-isoleucine-12-hydroxylase
ECTree
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Systematic Name
Systematic Name on EC 1.14.14.49 - 12-hydroxyjasmonoyl-L-amino acid 12-hydroxylase
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12-hydroxyjasmonoyl-L-amino acid,[reduced NADPH-hemoprotein reductase]:oxygen oxidoreductase (12-hydroxylating)
A cytochrome P450 (heme thiolate) enzyme found in plants. The enzyme acts on jasmonoyl-L-amino acid conjugates that have been hydroxylated at the C-12 position of jasmonic acid by EC 1.14.14.48, jasmonoyl-L-amino acid 12-hydroxylase, further oxidizing that position to a carboxylate via an aldehyde intermediate. While the best studied substrate is (+)-7-epi-jasmonoyl-L-isoleucine, the enzyme was shown to be active with jasmonoyl-L-phenylalanine, and is likely to be active with other jasmonoyl-amino acid conjugates.