1.14.14.51: (S)-limonene 6-monooxygenase
This is an abbreviated version!
For detailed information about (S)-limonene 6-monooxygenase, go to the full flat file.
Word Map on EC 1.14.14.51
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1.14.14.51
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spearmint
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monoterpene
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regiospecific
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peppermint
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olefin
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carvone
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mentha
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trans-carveol
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limonene-3-hydroxylase
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regiochemistry
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hydroxylases
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geranyl
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p-menthane
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conversions
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perillyl
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facial
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carveol
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p450-catalyzed
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piperita
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allylic
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monoterpenoids
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stereochemistry
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enantiomers
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stereochemical
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fad
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complementarity
- 1.14.14.51
- spearmint
-
monoterpene
-
regiospecific
- peppermint
-
olefin
- carvone
- mentha
-
trans-carveol
- limonene-3-hydroxylase
-
regiochemistry
- hydroxylases
-
geranyl
-
p-menthane
-
conversions
-
perillyl
-
facial
- carveol
-
p450-catalyzed
- piperita
-
allylic
-
monoterpenoids
-
stereochemistry
-
enantiomers
-
stereochemical
- fad
-
complementarity
Reaction
Synonyms
(+)-limonene-6-hydroxylase, (-)-(4S)-limonene-6-hydroxylase, (-)-limonene 6-hydroxylase, (-)-limonene 6-monooxygenase, (-)-limonene,NADPH:oxygen oxidoreductase (6-hydroxylating), (-)-limonene-6-hydroxylase, 4S-limonene-6-hydroxylase, EC 1.14.13.48, limonene hydroxylase, limonene-6-hydroxylase, oxygenase, (-)-limonene 6-mono-
ECTree
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Reference
Reference on EC 1.14.14.51 - (S)-limonene 6-monooxygenase
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Gershenzon, J.; Maffei, M.; Croteau, R.
Biochemical and histochemical localization of monoterpene biosynthesis in the glandular trichomes of spearmint (Mentha spicata)
Plant Physiol.
89
1351-1357
1989
Mentha spicata
Karp, F.; Mihaliak, C.A.; Harris, J.L.; Croteau, R.
Monoterpene biosynthesis: specificity of the hydroxylations of (-)-limonene by enzyme preparations from peppermint (Mentha piperita), spearmint (Mentha spicata), and perilla (Perilla frutescens) leaves
Arch. Biochem. Biophys.
276
219-226
1990
Mentha spicata
Croteau, R.; Karp, F.; Wagschal, K.C.; Satterwhite, M.; Hyatt, D.C.; Skotland, C.B.
Biochemical characterization of a spearmint mutant that resembles peppermint in monoterpene content
Plant Physiol.
96
744-752
1991
Mentha x gracilis
Gershenzon, J.; McCaskill, D.; Rajaonarivony, J.I.; Mihaliak, C.; Karp, F.; Croteau, R.
Isolation of secretory cells from plant glandular trichomes and their use in biosynthetic studies of monoterpenes and other gland products
Anal. Biochem.
200
130-138
1992
Mentha spicata
Schalk, M.; Croteau, R.
A single amino acid substitution (F363I) converts the regiochemistry of the spearmint (-)-limonene hydroxylase from a C6- to a C3-hydroxylase
Proc. Natl. Acad. Sci. USA
97
11948-11953
2000
Mentha spicata
Lupien, S.; Karp, F.; Wildung, M.; Croteau, R.
Regiospecific cytochrome P450 limonene hydroxylases from mint (Mentha) species: cDNA isolation, characterization, and functional expression of (-)-4S-limonene-3-hydroxylase and (-)-4S-limonene-6-hydroxylase
Arch. Biochem. Biophys.
368
181-192
1999
Mentha spicata (Q9XHE8), Mentha spicata
Haudenschild, C.; Schalk, M.; Karp, F.; Croteau, R.
Functional expression of regiospecific cytochrome P450 limonene hydroxylases from mint (Mentha spp.) in Escherichia coli and Saccharomyces cerevisiae
Arch. Biochem. Biophys.
379
127-136
2000
Mentha spicata
Wust, M.; Little, D.B.; Schalk, M.; Croteau, R.
Hydroxylation of limonene enantiomers and analogs by recombinant (-)-limonene 3- and 6-hydroxylases from Mint (Mentha) species: Evidence for catalysis within sterically constrained active sites
Arch. Biochem. Biophys.
387
125-136
2001
Mentha spicata
Wuest, M.; Croteau, R.B.
Hydroxylation of specifically deuterated limonene enantiomers by cytochrome P450 limonene-6-hydroxylase reveals the mechanism of multiple product formation
Biochemistry
41
1820-1827
2002
Mentha spicata
Lupien, S.; Karp, F.; Ponnamperuma, K.; Wildung, M.; Croteau, R.
Cytochrome P450 limonene hydroxylases of Mentha species
Drug Metabol. Drug Interact.
12
245-260
1995
Mentha spicata
Carter, O.A.; Peters, R.J.; Croteau, R.
Monoterpene biosynthesis pathway construction in Escherichia coli
Phytochemistry
64
425-433
2003
Mentha spicata
Shimada, T.; Shindo, M.; Miyazawa, M.
Species differences in the metabolism of (+)- and (-)-limonenes and their metabolites, carveols and carvones, by cytochrome P450 enzymes in liver microsomes of mice, rats, guinea pigs, rabbits, dogs, monkeys, and humans
Drug Metab. Pharmacokinet.
17
507-515
2002
Canis lupus familiaris, Cavia porcellus, Oryctolagus cuniculus, Macaca fascicularis, Homo sapiens, Mus musculus, Rattus norvegicus
Turner, G.W.; Croteau, R.
Organization of monoterpene biosynthesis in Mentha. Immunocytochemical localizations of geranyl diphosphate synthase, limonene-6-hydroxylase, isopiperitenol dehydrogenase, and pulegone reductase
Plant Physiol.
136
4215-4227
2004
Mentha spicata
Hamada, H.; Kondo, Y.; Ishihara, K.; Nakajima, N.; Kurihara, R.; Hirata, T.
Stereoselective biotransformation of limonene and limonene oxide by cyanobacterium, Synechococcus sp. PCC 7942
J. Biosci. Bioeng.
96
581-584
2003
Synechococcus sp., Synechococcus sp. PCC 7942
Cheong, T.; Oriel, P.
Cloning and expression of the limonene hydroxylase of Bacillus stearothermophilus BR388 and utilization in two-phase limonene conversions
Appl. Biochem. Biotechnol.
84-86
903-915
2000
Geobacillus stearothermophilus (O85057), Geobacillus stearothermophilus, Geobacillus stearothermophilus BR388 (O85057)
Bouwmeester, H.; Konings, M.; Gershenzon, J.; Karp, F.; Croteau, R.
Cytochrome P-450 dependent (+)-limonene-6-hydroxylation in fruits of caraway (Carum carvi)
Phytochemistry
50
243-248
1999
Carum carvi
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