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1.14.14.59: dimethylnonatriene synthase

This is an abbreviated version!
For detailed information about dimethylnonatriene synthase, go to the full flat file.

Reaction

(3S,6E)-nerolidol
+
[reduced NADPH-hemoprotein reductase]
+
O2
=
(3E)-4,8-dimethylnona-1,3,7-triene
+
[oxidized NADPH-hemoprotein reductase]
+
but-3-en-2-one
+ 2 H2O

Synonyms

At3g25180, CYP82G1, CYP92C5, DMNT/TMTT homoterpene synthase

ECTree

     1 Oxidoreductases
         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen
             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
                1.14.14.59 dimethylnonatriene synthase

Systematic Name

Systematic Name on EC 1.14.14.59 - dimethylnonatriene synthase

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SYSTEMATIC NAME
IUBMB Comments
(3S,6E)-nerolidol,[reduced NADPH-hemoprotein reductase]:oxygen oxidoreductase
A cytochrome P-450 (heme-thiolate) protein isolated from the plants Arabidopsis thaliana (thale cress) and Zea mays (maize). It forms this C11 homoterpene in response to herbivore attack. In vitro the enzyme also converts (6E,10E)-geranyllinalool to (3E,7E)-4,8,12-trimethyltrideca-1,3,7,11-tetraene (see EC 1.14.14.58, trimethyltridecatetraene synthase).