1.2.1.58: phenylglyoxylate dehydrogenase (acylating)

This is an abbreviated version!
For detailed information about phenylglyoxylate dehydrogenase (acylating), go to the full flat file.

Reaction

phenylglyoxylate
+
NAD+
+
CoA
=
benzoyl-S-CoA
+
CO2
+
NADH

Synonyms

Dehydrogenase, phenylglyoxylate (CoA-benzoylating), Phenylglyoxal:NAD+ oxidoreductase (CoA benzoylating), Phenylglyoxylate dehydrogenase (CoA benzoylating), Phenylglyoxylate-acceptor oxidoreductase, Phenylglyoxylate:acceptor oxidoreductase

ECTree

     1 Oxidoreductases
         1.2 Acting on the aldehyde or oxo group of donors
             1.2.1 With NAD+ or NADP+ as acceptor
                1.2.1.58 phenylglyoxylate dehydrogenase (acylating)

Substrates Products

Substrates Products on EC 1.2.1.58 - phenylglyoxylate dehydrogenase (acylating)

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SUBSTRATE
PRODUCT                       
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate) hide
LITERATURE
(Substrate)
COMMENTARY
(Product) hide
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
2-oxoisovalerate + NAD+ + CoA-SH
?
show the reaction diagram
-
at 15% of the activity relative to phenylglyoxylate
-
-
?
phenylglyoxylate + benzyl viologen + CoA-SH
benzoyl-S-CoA + CO2 + reduced benzyl viologen
show the reaction diagram
phenylglyoxylate + FAD + CoA-SH
benzoyl-S-CoA + CO2 + FADH2
show the reaction diagram
-
-
-
-
?
phenylglyoxylate + FMN + CoA-SH
benzoyl-S-CoA + CO2 + FMNH
show the reaction diagram
-
-
-
-
?
phenylglyoxylate + methyl viologen + CoA-SH
benzoyl-S-CoA + CO2 + reduced methyl viologen
show the reaction diagram
-
-
-
-
?
phenylglyoxylate + NAD+ + CoA-SH
benzoyl-S-CoA + CO2 + NADH
show the reaction diagram
additional information
?
-
-
enzyme catalyzes a NAD(H):viologen dye transhydrogenation
-
-
?