1.3.1.123: 8-oxogeranial reductase

This is an abbreviated version!
For detailed information about 8-oxogeranial reductase, go to the full flat file.

Reaction

(R)-8-oxocitronellyl enol
+
NADP+
=
(6E)-8-oxogeranial
+
NADPH
+
H+

Synonyms

AmISY

ECTree

     1 Oxidoreductases
         1.3 Acting on the CH-CH group of donors
             1.3.1 With NAD+ or NADP+ as acceptor
                1.3.1.123 8-oxogeranial reductase

Advanced search results

Do not include text mining results
Include results (more...)
Include results (more...)

Systematic Name

Systematic Name on EC 1.3.1.123 - 8-oxogeranial reductase

Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
SYSTEMATIC NAME
IUBMB Comments
(R)-8-oxocitronellyl enol:NADP+ oxidoreductase
The enzyme, characterized from the plant Antirrhinum majus (snapdragon), is involved in biosynthesis of 7-epi-iridoids such as antirrhinoside. The enzyme catalyses the stereospecific reduction of 8-oxogeranial, forming an unstable product that in the absence of additional cylases undergoes spontaneous cyclization to (-)-cis,trans-nepetalactol. cf. EC 1.3.1.122, (S)-8-oxocitronellyl enol synthase.