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EC 2.7.8.23 Details
EC number
2.7.8.23
Accepted name
carboxyvinyl-carboxyphosphonate phosphorylmutase
Reaction
1-carboxyvinyl carboxyphosphonate = 3-(hydroxyphosphinoyl)pyruvate + CO2
Systematic name
1-carboxyvinyl carboxyphosphonate phosphorylmutase (decarboxylating)
CAS registry number
122799-57-9
Comment
Catalyses the transfer and decarboxylation of the carboxy(hydroxy)phosphoryl group, HOOC-P(O)(OH)- (phosphoryl being a 3-valent group), in the formation of an unusual C-P bond that is involved in the biosynthesis of the antibiotic bialaphos.
History
created 1999
EC Tree
2.8.2.12 created 1972, deleted 2001
2.8.3.4 created 1961, deleted 1964