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EC 5.3.3.18 Details
EC number
5.3.3.18
Accepted name
2-(1,2-epoxy-1,2-dihydrophenyl)acetyl-CoA isomerase
Reaction
2-(1,2-epoxy-1,2-dihydrophenyl)acetyl-CoA = 2-oxepin-2(3H)-ylideneacetyl-CoA
Other name(s)
paaG (gene name), 1,2-epoxyphenylacetyl-CoA isomerase (misleading)
Systematic name
2-(1,2-epoxy-1,2-dihydrophenyl)acetyl-CoA isomerase
Comment
The enzyme catalyses the reversible isomerization of 2-(1,2-epoxy-1,2-dihydrophenyl)acetyl-CoA to the unusual unsaturated, oxygen-containing, seven-member heterocyclic enol ether 2-oxepin-2(3H)-ylideneacetyl-CoA, as part of an aerobic phenylacetate degradation pathway.
History
created 2011
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