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EC Tree
IUBMB Comments Oxidation on the 4-position of the hexose moiety takes place only while the substrate is bound to another enzyme that catalyses epimerization at C-3 and C-5.
The expected taxonomic range for this enzyme is: Escherichia coli
Synonyms
dehydrogenase, thymidine diphospho-6-deoxy-L-talose, dTDP-6-deoxy-L-talose dehydrogenase (4-reductase), TDP-6-deoxy-L-talose dehydrogenase, thymidine diphospho-6-deoxy-L-talose dehydrogenase,
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dehydrogenase, thymidine diphospho-6-deoxy-L-talose
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dTDP-6-deoxy-L-talose dehydrogenase (4-reductase)
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TDP-6-deoxy-L-talose dehydrogenase
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thymidine diphospho-6-deoxy-L-talose dehydrogenase
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dTDP-6-deoxy-beta-L-talose + NADP+ = dTDP-4-dehydro-beta-L-rhamnose + NADPH + H+
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dTDP-6-deoxy-beta-L-talose:NADP+ 4-oxidoreductase
Oxidation on the 4-position of the hexose moiety takes place only while the substrate is bound to another enzyme that catalyses epimerization at C-3 and C-5.
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TDP-6-deoxy-D-xylo-4-hexosulose + NADPH
TDP-6-deoxy-L-talose + NADP+
TDP-6-deoxy-D-xylo-4-hexosulose + NADPH
TDP-6-deoxy-L-talose + NADP+
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via TDP-6-deoxy-L-lyxo-4-hexosulose, enzyme-bound intermediate
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TDP-6-deoxy-D-xylo-4-hexosulose + NADPH
TDP-6-deoxy-L-talose + NADP+
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via TDP-6-deoxy-L-lyxo-4-hexosulose, enzyme-bound intermediate
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TDP-6-deoxy-D-xylo-4-hexosulose + NADPH
TDP-6-deoxy-L-talose + NADP+
TDP-6-deoxy-D-xylo-4-hexosulose + NADPH
TDP-6-deoxy-L-talose + NADP+
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TDP-6-deoxy-D-xylo-4-hexosulose + NADPH
TDP-6-deoxy-L-talose + NADP+
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Gaugler, R.W.; Gabriel, O.
Biological mechanisms involved in the formation of deoxy sugars. VII. Biosynthesis of 6-deoxy-L-talose
J. Biol. Chem.
248
6041-6049
1973
Escherichia coli, Escherichia coli 45
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