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Information on EC 1.1.1.297 - limonene-1,2-diol dehydrogenase for references in articles please use BRENDA:EC1.1.1.297
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IUBMB Comments While the enzyme from the Gram-positive bacterium Rhodococcus erythropolis DCL14 can use both (1S,2S,4R)- and (1R,2R,4S)-menth-8-ene-1,2-diol as substrate, activity is higher with (1S,2S,4R)-menth-8-ene-1,2-diol as substrate.
The expected taxonomic range for this enzyme is: Rhodococcus erythropolis
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(1R,2R,4S)-menth-8-ene-1,2-diol + NAD+ = (1R,4S)-1-hydroxymenth-8-en-2-one + NADH + H+
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(1S,2S,4R)-menth-8-ene-1,2-diol + NAD+ = (1S,4R)-1-hydroxymenth-8-en-2-one + NADH + H+
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menth-8-ene-1,2-diol + NAD+ = 1-hydroxymenth-8-en-2-one + NADH + H+
general reaction
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menth-8-ene-1,2-diol:NAD+ oxidoreductase
While the enzyme from the Gram-positive bacterium Rhodococcus erythropolis DCL14 can use both (1S,2S,4R)- and (1R,2R,4S)-menth-8-ene-1,2-diol as substrate, activity is higher with (1S,2S,4R)-menth-8-ene-1,2-diol as substrate.
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(1R,2R,4S)-limonene-1,2-diol + NAD+
(1R,4S)-1-hydroxy-2-oxolimonene + (1R,2S,4S)-limonene-1,2-diol + NADH + H+
(1S,2S,4R)-limonene-1,2-diol + NAD+
(1S,4R)-1-hydroxy-2-oxolimonene + NADH + H+
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(1R,2R,4S)-limonene-1,2-diol + NAD+
(1R,4S)-1-hydroxy-2-oxolimonene + (1R,2S,4S)-limonene-1,2-diol + NADH + H+
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(1R,2R,4S)-limonene-1,2-diol + NAD+
(1R,4S)-1-hydroxy-2-oxolimonene + (1R,2S,4S)-limonene-1,2-diol + NADH + H+
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(1S,2S,4R)-limonene-1,2-diol + NAD+
(1S,4R)-1-hydroxy-2-oxolimonene + NADH + H+
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(1S,2S,4R)-limonene-1,2-diol + NAD+
(1S,4R)-1-hydroxy-2-oxolimonene + NADH + H+
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enzymatic activities is involved in the limonene degradation pathway
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enzymatic activities is involved in the limonene degradation pathway
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additional information
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additional information
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enzymatic activities is involved in the limonene degradation pathway
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enzymatic activities is involved in the limonene degradation pathway
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DCL14
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DCL14
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van der Werf, M.J.; Swarts, H.J.; de Bont, J.A.
Rhodococcus erythropolis DCL14 contains a novel degradation pathway for limonene
Appl. Environ. Microbiol.
65
2092-2102
1999
Rhodococcus erythropolis, Rhodococcus erythropolis DCL14
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Enzyme Nomenclature
1.1.1.297 limonene-1,2-diol dehydrogenase
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