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IUBMB Comments The enzyme has been characterized from the bacterium Aggregatibacter actinomycetemcomitans , in which it participates in the biosynthesis of the serotype c-specific polysaccharide antigen. Shows no activity with NADP+
Synonyms tll ,
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dTDP-6-deoxy-L-lyxo-4-hexulose reductase
dTDP-6-deoxy-L-lyxo-4-hexulose reductase
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dTDP-6-deoxy-L-lyxo-4-hexulose reductase
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tll
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dTDP-6-deoxy-beta-L-talose + NAD+ = dTDP-4-dehydro-beta-L-rhamnose + NADH + H+
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MetaCyc
superpathway of dTDP-glucose-derived O-antigen building blocks biosynthesis
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dTDP-6-deoxy-beta-L-talose:NAD+ 4-oxidoreductase
The enzyme has been characterized from the bacterium Aggregatibacter actinomycetemcomitans, in which it participates in the biosynthesis of the serotype c-specific polysaccharide antigen. Shows no activity with NADP+.
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dTDP-4-dehydro-6-deoxy-beta-L-mannose + NADH + H+
dTDP-6-deoxy-beta-L-talose + NAD+
dTDP-4-dehydro-6-deoxy-beta-L-mannose + NADH + H+
dTDP-6-deoxy-beta-L-talose + NAD+
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Substrates: -
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dTDP-4-dehydro-6-deoxy-beta-L-mannose + NADH + H+
dTDP-6-deoxy-beta-L-talose + NAD+
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Substrates: -
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NCTC 9710
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physiological function
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enzyme is part of the pathway leading to the unusual sugar, 6-deoxy-L-talose, which is a conctituent of cell wall components in some bacteria
physiological function
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enzyme is part of the pathway leading to the unusual sugar, 6-deoxy-L-talose, which is a conctituent of cell wall components in some bacteria
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TLL_AGGAC
270
0
30680
Swiss-Prot
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30700
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x * 30700, SDS-PAGE
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x * 30700, SDS-PAGE
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x * 30700, SDS-PAGE
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expression in Escherichia coli
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Nakano, Y.; Suzuki, N.; Yoshida, Y.; Nezu, T.; Yamashita, Y.; Koga, T.
Thymidine diphosphate-6-deoxy-L-lyxo-4-hexulose reductase synthesizing dTDP-6-deoxy-L-talose from Actinobacillus actinomycetemcomitans
J. Biol. Chem.
275
6806-6812
2000
Aggregatibacter actinomycetemcomitans
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