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Information on EC 1.1.3.42 - prosolanapyrone-II oxidase

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EC Tree
     1 Oxidoreductases
         1.1 Acting on the CH-OH group of donors
             1.1.3 With oxygen as acceptor
                1.1.3.42 prosolanapyrone-II oxidase
IUBMB Comments
The enzyme is involved in the biosynthesis of the phytotoxin solanapyrone by some fungi. The bifunctional enzyme catalyses the oxidation of prosolanapyrone II and the subsequent Diels Alder cycloisomerization of the product prosolanapyrone III to (-)-solanapyrone A (cf. EC 5.5.1.20, prosolanapyrone III cycloisomerase).
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Word Map
  • 1.1.3.42
  • alternaria
  • diels-alder
  • solani
  • iterative
  • polyketide
  • diels-alderase
  • cycloaddition
The enzyme appears in viruses and cellular organisms
Synonyms
solanapyrone synthase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
prosolanapyrone II + O2 = prosolanapyrone III + H2O2
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