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Information on EC 1.1.3.47 - 5-(hydroxymethyl)furfural oxidase

for references in articles please use BRENDA:EC1.1.3.47

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IUBMB Comments

The enzyme, characterized from the bacterium Methylovorus sp. strain MP688, is involved in the degradation and detoxification of 5-(hydroxymethyl)furfural. The enzyme acts only on alcohol groups and requires the spontaneous hydration of aldehyde groups for their oxidation . The enzyme has a broad substrate range that overlaps with EC 1.1.3.7, aryl-alcohol oxidase.

The expected taxonomic range for this enzyme is: Bacteria, Eukaryota
Reaction Schemes
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5-(hydroxymethyl)furfural
+
3
O2
+
2
H2O
=
furan-2,5-dicarboxylate
+
3
H2O2
+
3
+
2
=
+
3

Synonyms
5-hydroxymethylfurfural oxidase, hmf oxidase, hmf/furfural oxidoreductase, 5-(hydroxymethyl)furfural oxidase, more

REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
5-(dihydroxymethyl)furan-2-carbaldehyde + O2 = 5-formylfuran-2-carboxylate + H2O2
show the reaction diagram
(1c)
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-
-
5-(dihydroxymethyl)furan-2-carboxylate + O2 = furan-2,5-dicarboxylate + H2O2
show the reaction diagram
(1e)
-
-
-
5-(hydroxymethyl)furfural + 3 O2 + 2 H2O = furan-2,5-dicarboxylate + 3 H2O2
show the reaction diagram
overall reaction
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-
-
5-(hydroxymethyl)furfural + O2 = furan-2,5-dicarbaldehyde + H2O2
show the reaction diagram
(1a)
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-
-
5-formylfuran-2-carboxylate + H2O = 5-(dihydroxymethyl)furan-2-carboxylate
show the reaction diagram
(1d), spontaneous
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-
-
furan-2,5-dicarbaldehyde + H2O = 5-(dihydroxymethyl)furan-2-carbaldehyde
show the reaction diagram
(1b), spontaneous
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