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IUBMB CommentsThe product decomposes spontaneously to 6-oxohexanoic acid (adipic semialdehyde).
The expected taxonomic range for this enzyme is: Acinetobacter sp.
Synonyms
2-Hydroxycyclohexan-1-one monooxygenase, EC 1.14.12.6, Oxygenase, 2-hydroxycyclohexanone 2-mono-,
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2-Hydroxycyclohexan-1-one monooxygenase
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EC 1.14.12.6
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Oxygenase, 2-hydroxycyclohexanone 2-mono-
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2-hydroxycyclohexan-1-one + NADPH + H+ + O2 = 6-hydroxyhexan-6-olide + NADP+ + H2O
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2-hydroxycyclohexan-1-one,NADPH:oxygen 2-oxidoreductase (1,2-lactonizing)
The product decomposes spontaneously to 6-oxohexanoic acid (adipic semialdehyde).
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2-hydroxycyclohexan-1-one + NADPH + O2
1-oxa-2-oxo-7-hydroxycycloheptane + NADP+ + H2O
2-Hydroxycyclohexan-1-one + NADPH + O2
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enzyme in the oxidation pathway of trans-cyclohexan-1,2-diol to adipate, enzyme activity is induced by trans-cyclohexan-1,2-diol
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2-Methylcyclohexanone + NADPH + O2
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3-Methylcyclohexanone + NADPH + O2
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4-Methylcyclohexanone + NADPH + O2
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Cyclohexanone + NADPH + O2
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2-hydroxycyclohexan-1-one + NADPH + O2
1-oxa-2-oxo-7-hydroxycycloheptane + NADP+ + H2O
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1-oxa-2-oxo-7-hydroxycycloheptane spontaneously rearranges to yield 6-oxohexanoate
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2-hydroxycyclohexan-1-one + NADPH + O2
1-oxa-2-oxo-7-hydroxycycloheptane + NADP+ + H2O
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1-oxa-2-oxo-7-hydroxycycloheptane spontaneously rearranges to yield 6-oxohexanoate
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2-hydroxycyclohexan-1-one + NADPH + O2
1-oxa-2-oxo-7-hydroxycycloheptane + NADP+ + H2O
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1-oxa-2-oxo-7-hydroxycycloheptane spontaneously rearranges to yield 6-oxohexanoate
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2-Methylcyclohexanone + NADPH + O2
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2-Methylcyclohexanone + NADPH + O2
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2-Methylcyclohexanone + NADPH + O2
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3-Methylcyclohexanone + NADPH + O2
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3-Methylcyclohexanone + NADPH + O2
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3-Methylcyclohexanone + NADPH + O2
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4-Methylcyclohexanone + NADPH + O2
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4-Methylcyclohexanone + NADPH + O2
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4-Methylcyclohexanone + NADPH + O2
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Cyclohexanone + NADPH + O2
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Cyclohexanone + NADPH + O2
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Cyclohexanone + NADPH + O2
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2-Hydroxycyclohexan-1-one + NADPH + O2
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enzyme in the oxidation pathway of trans-cyclohexan-1,2-diol to adipate, enzyme activity is induced by trans-cyclohexan-1,2-diol
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0.0062
2-Hydroxycyclohexan-1-one
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TD63
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brenda
TD63
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brenda
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Davey, J.F.; Trudgill, P.W.
The metabolism of trans-cyclohexan-1,2-diol by an Acinetobacter species
Eur. J. Biochem.
74
115-127
1977
Acinetobacter sp., Acinetobacter sp. TD63
brenda
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1.14.13.66 2-hydroxycyclohexanone 2-monooxygenase
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