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Information on EC 1.14.14.135 - glyceollin synthase

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IUBMB Comments
A heme-thiolate protein (P-450). Glyceollins II and III are formed from 2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan whereas glyceollin I is formed from the 4-isomer.
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The expected taxonomic range for this enzyme is: Glycine max
Synonyms
dimethylallyl-3,6a,9-trihydroxypterocarpan cyclase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin II + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin III + [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
(2)
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4-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin I + [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
(3)
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